Harkins, Seth B. and Peters, Jonas C. (2005) Highly emissive, redox active amido-bridged Cu_2N_2 diamond core complexes supported by phosphine ligands. Abstracts of Papers of the American Chemical Society, 229 . INOR 403. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140729-145420932
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Abstract
A series of novel Cu_2N_2 diamond core structures supported by P_2N- ligands have been prepd. These diamond core systems exhibit reversible 1-electron redox processes between the Cu^1Cu^1, [CuCu]^+, [CuCu]^2+ states. The solid-state mol. structures of each show that minimal overall structural reorganization occurs, though minor core distortions are present. Addnl., the Cu^1Cu^1, form is highly emissive (φ > 65%, τ > 10 μs) and gives rise to interesting photoreductive chem. The magnetic, electrochem. and spectroscopic data, as well as initial reactivity studies, will be discussed.
Item Type: | Article | ||||
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ORCID: |
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Alternate Title: | Highly emissive, redox active amido-bridged Cu2N2 diamond core complexes supported by phosphine ligands | ||||
Additional Information: | © 2005 American Chemical Society. | ||||
Record Number: | CaltechAUTHORS:20140729-145420932 | ||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140729-145420932 | ||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
ID Code: | 47568 | ||||
Collection: | CaltechAUTHORS | ||||
Deposited By: | Tony Diaz | ||||
Deposited On: | 30 Jul 2014 18:42 | ||||
Last Modified: | 26 Nov 2019 11:15 |
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