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Highly emissive, redox active amido-bridged Cu_2N_2 diamond core complexes supported by phosphine ligands

Harkins, Seth B. and Peters, Jonas C. (2005) Highly emissive, redox active amido-bridged Cu_2N_2 diamond core complexes supported by phosphine ligands. Abstracts of Papers of the American Chemical Society, 229 . INOR 403. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140729-145420932

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Abstract

A series of novel Cu_2N_2 diamond core structures supported by P_2N- ligands have been prepd. These diamond core systems exhibit reversible 1-electron redox processes between the Cu^1Cu^1, [CuCu]^+, [CuCu]^2+ states. The solid-state mol. structures of each show that minimal overall structural reorganization occurs, though minor core distortions are present. Addnl., the Cu^1Cu^1, form is highly emissive (φ > 65%, τ > 10 μs) and gives rise to interesting photoreductive chem. The magnetic, electrochem. and spectroscopic data, as well as initial reactivity studies, will be discussed.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Alternate Title:Highly emissive, redox active amido-bridged Cu2N2 diamond core complexes supported by phosphine ligands
Additional Information:© 2005 American Chemical Society.
Record Number:CaltechAUTHORS:20140729-145420932
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140729-145420932
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47568
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:30 Jul 2014 18:42
Last Modified:26 Nov 2019 11:15

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