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Electrocatalytic hydrogen evolution with first-row metals: A bimetallic approach

Mendiratta, Arjun and Peters, Jonas C. (2006) Electrocatalytic hydrogen evolution with first-row metals: A bimetallic approach. Abstracts of Papers of the American Chemical Society, 232 . INOR 014. ISSN 0065-7727.

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A new family of dinucleating ligands has been designed and their dicobalt complexes synthesized. The ability of these compds. to catalyze the redn. of protons to dihydrogen has been thoroughly investigated using both electrochem. and spectroscopic methods. Structure-function relationships and mechanistic proposals are presented and comparisons are made both to mononuclear analogs and to the bimetallic active site of Fe-only hydrogenase.

Item Type:Article
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2006 American Chemical Society.
Record Number:CaltechAUTHORS:20140730-080709798
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47578
Deposited By: Tony Diaz
Deposited On:30 Jul 2014 17:31
Last Modified:26 Nov 2019 11:15

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