Saouma, Caroline T. and Peters, Jonas C. (2007) Carbon dioxide activation by low-valent pseudo-tetrahedral iron. Abstracts of Papers of the American Chemical Society, 234 . INOR 920. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140730-132553802
Full text is not posted in this repository.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20140730-132553802
Abstract
Upon exposure to CO_2, pseudo-tetrahedral iron(I) supported by 1;PhBP^R_33;- ligands (where 1;PhBP^R_33; =1;PhB(CH_2PR2)_33;-, and R = CH_2Cy, ^iPr, and Ph) effects either the reductive cleavage of CO_2 via O-atom transfer or reductive coupling of CO_2 to give an oxalate. THF solns. of 1;PhBP^(CH2Cy)_33;Fe(I) gives rise to the structurally unprecedented- Fe_2(μ-O)(μ-CO), whereas 1;PhBP^(CH2Cy)_33;FePPh_3 gives a bridging oxalate species. In situ sodium/amalgam redns. of 1;PhBP^R_33;FeCl under an atm. of CO_2 again gives Fe_2(μ-oxalate) for R =CH_2Cy, but gives a Fe_2O species as the major product for both R = -^iPr and Ph.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| ORCID: |
| ||||
| Additional Information: | © 2007 American Chemical Society. | ||||
| Record Number: | CaltechAUTHORS:20140730-132553802 | ||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140730-132553802 | ||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 47676 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | Tony Diaz | ||||
| Deposited On: | 31 Jul 2014 16:17 | ||||
| Last Modified: | 26 Nov 2019 11:15 |
Repository Staff Only: item control page
