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Homogeneous cobalt electrocatalysts for solar driven hydrogen evolution from water

Stubbert, Bryan D. and Peters, Jonas C. and Gray, Harry B. (2011) Homogeneous cobalt electrocatalysts for solar driven hydrogen evolution from water. Abstracts of Papers of the American Chemical Society, 242 . INOR 489. ISSN 0065-7727 . https://resolver.caltech.edu/CaltechAUTHORS:20140804-135735898

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Abstract

Towards the bigger picture of developing modular solns. for photoelectrochem. water splitting, catalytic proton redn. mediated by cobalt bis(iminopyridine) complexes has been explored in buffered aq. media over a broad range of pH conditions. The extremely rapid rates of electrocatalytic hydrogen evolution exhibited by firstgeneration catalysts will be discussed in conjunction with the performance of second-generation electrocatalysts. Details of electrochem. and photochem. mechanistic studies, kinetic competency, and the effects of reaction medium on H_2 evolution will also be presented.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 2011 American Chemical Society.
Record Number:CaltechAUTHORS:20140804-135735898
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140804-135735898
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47915
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:04 Aug 2014 21:35
Last Modified:26 Nov 2019 11:15

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