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The Diamagnetic Anisotropy of Aromatic Molecules

Pauling, Linus (1936) The Diamagnetic Anisotropy of Aromatic Molecules. Journal of Chemical Physics, 4 (10). pp. 673-677. ISSN 0021-9606. https://resolver.caltech.edu/CaltechAUTHORS:20140805-121913787

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Abstract

Values of the diamagnetic anisotropy of benzene and other aromatic hydrocarbon molecules are calculated on the basis of the assumption that the p_z electrons (one per aromatic carbon atom) are free to move from carbon atom to adjacent carbon atom under the influence of the impressed fields. When combined with the assumed values for the contributions of the other electrons (‐2.0×10^(‐6) for hydrogen, ‐4.5×10^(‐6) for aromatic carbon, ‐6.0×10^(‐6) for aliphatic carbon) these lead to principal diamagnetic susceptibilities of molecules in approximate agreement with the available experimental data. The diamagnetic anisotropy of graphite is also discussed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.1749766DOIArticle
http://scitation.aip.org/content/aip/journal/jcp/4/10/10.1063/1.1749766PublisherArticle
Additional Information:© 1936 American Institute of Physics. Received 11 July 1936.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates Chemical Laboratory555
Issue or Number:10
Record Number:CaltechAUTHORS:20140805-121913787
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140805-121913787
Official Citation:The Diamagnetic Anisotropy of Aromatic Molecules Pauling, Linus, The Journal of Chemical Physics, 4, 673-677 (1936), DOI:http://dx.doi.org/10.1063/1.1749766
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:47984
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:05 Aug 2014 20:01
Last Modified:03 Oct 2019 06:59

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