Hu, Xile and Cossairt, Brandi M. and Brunschwig, Bruce S. and Lewis, Nathan S. and Peters, Jonas C. (2005) Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications, 2005 (37). pp. 4723-4725. ISSN 1359-7345. doi:10.1039/b509188h. https://resolver.caltech.edu/CaltechAUTHORS:HUXcc05
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Abstract
In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.
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| Additional Information: | © Royal Society of Chemistry 2005 Received (in Berkeley, CA, USA) 28th June 2005, Accepted 29th July 2005. First published on the web 23rd August 2005 For financial support we acknowledge the NSF through a Chemical Bonding Center (CBC). We also thank Prof. Alex Sessions for his generous help with the gas chromatography experiments. | ||||||||||||
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| Issue or Number: | 37 | ||||||||||||
| DOI: | 10.1039/b509188h | ||||||||||||
| Record Number: | CaltechAUTHORS:HUXcc05 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:HUXcc05 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 4825 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Archive Administrator | ||||||||||||
| Deposited On: | 08 Sep 2006 | ||||||||||||
| Last Modified: | 08 Nov 2021 20:20 |
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