Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Hu, Xile and Cossairt, Brandi M. and Brunschwig, Bruce S. and Lewis, Nathan S. and Peters, Jonas C. (2005) Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications, 2005 (37). pp. 4723-4725. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:HUXcc05

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Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:HUXcc05

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.

Item Type:

Article

ORCID:

Author	ORCID
Hu, Xile	0000-0001-8335-1196
Cossairt, Brandi M.	0000-0002-9891-3259
Brunschwig, Bruce S.	0000-0002-6135-6727
Lewis, Nathan S.	0000-0001-5245-0538
Peters, Jonas C.	0000-0002-6610-4414

Additional Information:

© Royal Society of Chemistry 2005 Received (in Berkeley, CA, USA) 28th June 2005, Accepted 29th July 2005. First published on the web 23rd August 2005 For financial support we acknowledge the NSF through a Chemical Bonding Center (CBC). We also thank Prof. Alex Sessions for his generous help with the gas chromatography experiments.

Funders:

Funding Agency	Grant Number
NSF	UNSPECIFIED

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Record Number:

CaltechAUTHORS:HUXcc05

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:HUXcc05

Alternative URL:

http://dx.doi.org/10.1039/b509188h

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ID Code:

4825

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CaltechAUTHORS

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Deposited On:

08 Sep 2006

Last Modified:

07 Oct 2019 17:29

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