CaltechAUTHORS
  A Caltech Library Service

Coordination chemistry of iron and cobalt supported by hybrid bis(phosphino) pyrazolylborate ligands

Thomas, Christine M. and Peters, Jonas C. (2006) Coordination chemistry of iron and cobalt supported by hybrid bis(phosphino) pyrazolylborate ligands. Abstracts of Papers of the American Chemical Society, 231 . INOR 734. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140811-083353060

Full text is not posted in this repository.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20140811-083353060

Abstract

Motivated by the unique and versatile late transition metal chem. that has been accessed using the tris(phosphino)borate ligands, a new hybrid ligand in which one of the phosphine arms has been replaced with a pyrazolyl moiety has been designed. The coordination chem. of this ligand has been explored using both iron and cobalt. Similar to the tris(phosphine) analogs, the bis(phosphino)pyrazolylborate hybrid ligands are capable of stabilizing both low valent FeI and CoI complexes as well as FeIII and CoIII terminal imides. The synthetic methodol. providing access to this ligand and its derivs. will be discussed and the differences in coordination chem. imparted by this ligand will be presented.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2006 American Chemical Society.
Record Number:CaltechAUTHORS:20140811-083353060
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140811-083353060
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48279
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:11 Aug 2014 16:05
Last Modified:26 Nov 2019 11:15

Repository Staff Only: item control page