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Two electron redox couples for hydrogen production

Peters, Jonas C. and Hu, Xile and Lewis, Nate and Brunschwig, Bruce B. and Coissart, Brandi M. (2006) Two electron redox couples for hydrogen production. Abstracts of Papers of the American Chemical Society, 231 . INOR 412. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20140811-083620961

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Abstract

As part of a collaborative, NSF-supported initiative to help develop the basic chem. needed for producing solar fuels, our group has been studying relatively inexpensive, first row transition metals that mediate electrocatalytic hydrogen evolution at unusually pos. potentials. These complexes constitute a severe structural departure from the active sites of hydrogenase enzymes, but are attractive candidates for hydrogen evolution because they access reduced states at quite pos. potentials that then trigger the two-electron redn. of proton to hydride. The systems are unusual in that they display remarkable tolerance to the typical hydrogenase poison, carbon monoxide. Our efforts to more fully map the chem. of these types of systems will be described.


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Hu, Xile0000-0001-8335-1196
Lewis, Nate0000-0001-5245-0538
Brunschwig, Bruce B.0000-0002-6135-6727
Coissart, Brandi M.0000-0002-9891-3259
Additional Information:© 2006 American Chemical Society.
Record Number:CaltechAUTHORS:20140811-083620961
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140811-083620961
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48280
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:11 Aug 2014 16:02
Last Modified:07 Oct 2019 17:38

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