Ung, Gael and Peters, Jonas C. (2014) Stabilization of mononuclear two-coordinate Fe(0) and Co(0) complexes. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140811-150719732
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Abstract
Low coordinate iron and cobalt complexes are sought after for their catalytic applications as well as their potential as bond activators. Most of the two-coordinate iron and cobalt species are in the formal +II oxidn. state, and are stabilized with extremely bulky X-type ligands. Formally zero-valent two-coordinate transition metal species are exceedingly rare and neither two-coordinate Fe(0) nor Co(0) complexes have been characterized to date. We will present the synthesis of neutral two-coordinate mononuclear iron and cobalt complexes using the vital cyclic (alkyl)(amino)carbenes as ligands. Their unusual properties and reactivity will also be discussed.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2014 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20140811-150719732 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140811-150719732 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 48345 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 11 Aug 2014 22:09 | ||||||
| Last Modified: | 09 Mar 2020 13:19 |
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