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Stabilization of mononuclear two-​coordinate Fe(0) and Co(0) complexes

Ung, Gael and Peters, Jonas C. (2014) Stabilization of mononuclear two-​coordinate Fe(0) and Co(0) complexes. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140811-150719732

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Abstract

Low coordinate iron and cobalt complexes are sought after for their catalytic applications as well as their potential as bond activators. Most of the two-coordinate iron and cobalt species are in the formal +II oxidn. state, and are stabilized with extremely bulky X-type ligands. Formally zero-valent two-coordinate transition metal species are exceedingly rare and neither two-coordinate Fe(0) nor Co(0) complexes have been characterized to date. We will present the synthesis of neutral two-coordinate mononuclear iron and cobalt complexes using the vital cyclic (alkyl)(amino)carbenes as ligands. Their unusual properties and reactivity will also be discussed.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/fall-2014.htmlOrganizationConference Website
ORCID:
AuthorORCID
Ung, Gael0000-0002-6313-3658
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20140811-150719732
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140811-150719732
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48345
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:11 Aug 2014 22:09
Last Modified:09 Mar 2020 13:19

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