Labinger, Jay A. (2014) Does cyclopentadienylirondicarbonyl dimer have a metal-metal bond? Who's asking? In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140812-125449216
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Abstract
Since its first synthesis in the early 1950s, the carbonyl-bridged dimer [CpFe(CO)_2]_2 has almost always been depicted with an explicit Fe-Fe bond (Figure 1a). In a recent article (Chem. Commun. (2012) 11481-11503), Green, Green and Parkin characterize that as a misrepresentation, and recommend that the mol. be shown as in Figure 2b. I will offer arguments for the traditional representation, with the Fe-Fe bond, as more appropriate in most situations. I will further suggest that the choice of how best to represent a mol. will generally be context-dependent, and support that claim by comparison to the process of translation between languages.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2014 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20140812-125449216 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140812-125449216 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 48397 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 12 Aug 2014 19:57 | ||||||
| Last Modified: | 03 Oct 2019 07:03 |
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