Lee, Heui Beom and Herbert, Dave E. and Suseno, Sandy and Agapie, Theodor (2014) Synthesis and reactivity of heteromultimetallic cobalt-oxido cluster complexes relevant to water oxidation. In: 248th American Chemical Society National Meeting & Exposition, 10-14 August 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140812-125909417
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Abstract
In recent years, heterogeneous mixed-metal systems contg. Co have gained increased attention as water oxidn. catalysts, but the role of the heterometal has not been fully elucidated. Similarly, the active site of the oxygen-evolving complex in photosystem II contains a heteromultimetallic [Mn_4CaO_n] site. The synthesis and reactivity of heteromutimetallic cobalt-oxido cluster complexes will be presented. Using a hexapyridyl-trialkoxide ligand, a trinuclear Co complex was used as a platform for the prepn. of tetrametallic oxido cluster complexes [MCo_3O]^n+ where M = Li^+, Zn^2+, Co^2+. Reactivity of such complexes toward oxygen atom transfer reagents and their redox properties will be discussed.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2014 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20140812-125909417 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140812-125909417 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 48400 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 12 Aug 2014 20:06 | ||||||
| Last Modified: | 28 Feb 2020 19:36 |
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