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Metal complexes supported by P-​arene-​P pincers

Agapie, Theodor (2014) Metal complexes supported by P-​arene-​P pincers. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140812-130150570

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Abstract

Multidentate phosphines connected by terphenyl linkers have been employed to support mono and multimetallic complexes. The central arene of the terphenyl unit acts as a labile ligand and coordinates in a variety of modes as a function of metal and oxidn. state. Addnl., this arene can be non-innocent with respect to redox and H-transfer chem. Variants with catechol and hydroquinone moieties show multi-proton, multi-electron transfer chem. The coordination chem. of these systems and studies of intra and intermol. reactivity for C-O, C-H, O-O bond activation and ammonia-borane dehydrogenation will be discussed.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/fall-2014.htmlOrganizationConference Website
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20140812-130150570
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140812-130150570
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48402
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 Aug 2014 20:05
Last Modified:03 Oct 2019 07:03

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