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Polymerization catalysis by bimetallic complexes

Sampson, Jessica and Radlauer, Madalyn and Agapie, Theodor (2014) Polymerization catalysis by bimetallic complexes. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA.

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Utilizing a rigid terphenyl linker appended with various donors, a series of bimetallic polymn. catalysts has been prepd. Access to meta and para substitution allows for modification of the metal-metal distance and the steric profiles. Bimetallic complexes supported by phenoxy-imine and bisphenoxy amine ligands have been prepd. and their chem. explored with early and late transition metals. These bimetallic catalysts have shown, depending on the nature of the metal, tolerance of amines, polymn. of amino olefins, and tacticity control. The mechanism of their polymn. of a variety of monomers will be discussed.

Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription Website
Radlauer, Madalyn0000-0002-3226-5340
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20140812-142845578
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48429
Deposited By: Tony Diaz
Deposited On:12 Aug 2014 21:31
Last Modified:09 Mar 2020 13:19

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