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m-​Terphenyl diphosphines bearing a central phenolate ring as coordinatively flexible frameworks for supporting transition metals

Low, Choon Heng and Edouard, Guy A. and Agapie, Theodor (2014) m-​Terphenyl diphosphines bearing a central phenolate ring as coordinatively flexible frameworks for supporting transition metals. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140812-143045742

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Abstract

Based on earlier studies of m-terphenyl-supported complexes, a m-terphenyl diphosphine framework bearing a central phenolate ring has been studied. This ligand framework imparts coordinative lability to stabilize metal centers of a variety of oxidn. states by shifting between arene/phenolate coordination. Metalation has been explored with iron, cobalt and nickel and their redox properties and reactivities will be discussed. Variations in the substituent para to the phenolate oxygen have been synthesized to investigate their electronic effects on the metal complex.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/fall-2014.htmlOrganizationConference Website
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20140812-143045742
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140812-143045742
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48431
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 Aug 2014 21:33
Last Modified:03 Oct 2019 07:03

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