Buss, Joshua A. and Cheng, Christine and Edouard, Guy A. and Shi, Jade and Agapie, Theodor (2014) Para-terphenyl diphosphine molybdenum complexes: Synthesis and reactivity. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140812-160025589
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20140812-160025589
Abstract
We describe the synthesis of a series of molybdenum (Mo) complexes supported by a para-terphenyl diphosphine (P2) ligand, displaying metal-arene interactions. Treatment of P2 with Mo tricarbonyl precursors yields the Mo°c species, P2Mo(CO)3. Two electron oxidn. followed by photolytic decarbonylation gives a Mo^II complex, [P2Mo(MeCN)2]^2+. Sodium azide oxidizes this species to yield a Mo^IV nitride-azide complex. Redn. with magnesium furnishes a Mo°c dinitrogen complex, P2Mo(N2). This dinitrogen species reacts cleanly with CO_2, H_2, or PhSiH_3 providing a μ_2-CO_2 complex, a Mo dihydride, and a Ph silyl hydride species, resp. The structure, characterization, and further reactivity of these P2 Mo complexes will be discussed.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||
| ORCID: |
| ||||||
| Additional Information: | © 2014 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20140812-160025589 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140812-160025589 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 48453 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 12 Aug 2014 23:04 | ||||||
| Last Modified: | 09 Mar 2020 13:18 |
Repository Staff Only: item control page
