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A Photochemical Model of the Martian Atmosphere

Nair, Hari and Allen, Mark and Anbar, Ariel D. and Yung, Yuk L. and Clancy, R. Todd (1994) A Photochemical Model of the Martian Atmosphere. Icarus, 111 (1). pp. 124-150. ISSN 0019-1035. https://resolver.caltech.edu/CaltechAUTHORS:20140813-082303033

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Abstract

The factors governing the amounts of CO, O_2, and O_3 in the martian atmosphere are investigated using a minimally constrained, one-dimensional photochemical model. We find that the incorporation of temperature-dependent CO_2 absorption cross sections leads to an enhancement in the water photolysis rate, increasing the abundance of OH radicals to the point where the model CO abundance is smaller than observed. Good agreement between models and observations of CO, O_2, O_3, and the escape flux of atomic hydrogen can be achieved, using only gas-phase chemistry, by varying the recommended rate constants for the reactions CO + OH and OH + HO_2 within their specified uncertainties. Similar revisions have been suggested to resolve discrepancies between models and observations of the terrestrial mesosphere. The oxygen escape flux plays a key role in the oxygen budget on Mars; as inferred from the observed atomic hydrogen escape, it is much larger than recent calculations of the exospheric escape rate for oxygen. Weathering of the surface may account for the imbalance. Quantification of the escape rates of oxygen and hydrogen from Mars is a worthwhile objective for an upcoming martian upper atmospheric mission. We also consider the possibility that HO_x radicals may be catalytically destroyed on dust grains suspended in the atmosphere. Good agreement with the observed CO mixing ratio can be achieved via this mechanism, but the resulting ozone column is much higher than the observed quantity. We feel that there is no need at this time to invoke heterogeneous processes to reconcile models and observations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1006/icar.1994.1137 DOIArticle
http://www.sciencedirect.com/science/article/pii/S0019103584711377PublisherArticle
http://dx.doi.org/10.1006/icar.1996.0184ErrataErratum
ORCID:
AuthorORCID
Yung, Yuk L.0000-0002-4263-2562
Additional Information:© 1994 by Academic Press, Inc. Received March 14 1994; revised May 31, 1994. We express our appreciation to J. L. Fox, who provided us with odd nitrogen production rates. We thank D. M. Hunten and V. A. Krasnopolsky for helpful comments during the review process. This work was supported by NASA Grant NAGW 2204 to the California Institute of Technology.
Funders:
Funding AgencyGrant Number
NASANAGW 2204
Issue or Number:1
Record Number:CaltechAUTHORS:20140813-082303033
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140813-082303033
Official Citation:Hari Nair, Mark Allen, Ariel D. Anbar, Yuk L. Yung, R.Todd Clancy, A Photochemical Model of the Martian Atmosphere, Icarus, Volume 111, Issue 1, September 1994, Pages 124-150, ISSN 0019-1035, http://dx.doi.org/10.1006/icar.1994.1137. (http://www.sciencedirect.com/science/article/pii/S0019103584711377)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48470
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Aug 2014 16:10
Last Modified:09 Mar 2020 13:19

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