Sattler, Aaron and Winkler, Jay R. and Labinger, Jay A. and Gray, Harry B. and Bercaw, John E. (2014) Upgrading light olefins by trimerization catalysis. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140813-091823187
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Abstract
Activation of a (phenoxy-imine) titanium tri-Me complex with one equiv. of B(C_6F_5)_3 effects the catalytic trimerization of ethylene. Stoichiometric activation with B(C_6F_5)_3 allows for mechanistic studies to be conducted, which give insight into catalyst initiation, trimerization, and decompn., and the relative rates of these processes. In addn. to ethylene, α-olefins are oligomerized with high selectivity for trimers (> 95%), of which approx. 85% are one regioisomer.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||
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| Additional Information: | © 2014 American Chemical Society. | ||||||||
| Record Number: | CaltechAUTHORS:20140813-091823187 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20140813-091823187 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 48486 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Tony Diaz | ||||||||
| Deposited On: | 13 Aug 2014 16:25 | ||||||||
| Last Modified: | 22 Nov 2019 09:58 |
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