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Chloryl Nitrate: A Novel Product of the OCIO + NO_3 + M Recombination

Friedl, Randall R. and Sander, Stanley P. and Yung, Yuk L. (1992) Chloryl Nitrate: A Novel Product of the OCIO + NO_3 + M Recombination. Journal of Physical Chemistry, 96 (19). pp. 7490-7493. ISSN 0022-3654. doi:10.1021/j100198a002. https://resolver.caltech.edu/CaltechAUTHORS:20140813-094930400

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Abstract

The products of the reaction of OClO with NO_3 were investigated between 220 and 298 K using a flow reactor and infrared, visible, and ultraviolet analysis. At temperatures below 250 K new infrared and ultraviolet absorption features were observed and assigned to the novel compound chloryl nitrate (O_2ClONO_2). Additionally, ClO and NO_2 were observed as reaction products, indicating the existence of a second reaction channel. O_2ClONO_2 formation predominates at temperatures below 230 K. The reaction rate constant at 220 K is estimated to be on the order of 10^(-14) cm^3 molecule^(-1) s^(-1) in 1-5 Torr of helium. These observations suggest that O_2ClONO_2 may exist in the terrestrial stratosphere.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://pubs.acs.org/doi/abs/10.1021/j100198a002PublisherArticle
http://dx.doi.org/10.1021/j100198a002DOIArticle
ORCID:
AuthorORCID
Sander, Stanley P.0000-0003-1424-3620
Yung, Yuk L.0000-0002-4263-2562
Alternate Title:Chloryl Nitrate: A Novel Product of the OCIO + NO3 + M Recombination
Additional Information:© 1992 American Chemical Society. Received: May 20, 1992: In Final Form: July 16, 1992. Part of the research described in this report was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under contract to the National Aeronautics and Space Administration. Y.L.Y. was supported by NASA Grant NAGW-413 to the California Institute of Technology.
Funders:
Funding AgencyGrant Number
NASA/JPL/CaltechUNSPECIFIED
NASANAGW-413
Issue or Number:19
DOI:10.1021/j100198a002
Record Number:CaltechAUTHORS:20140813-094930400
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140813-094930400
Official Citation:Chloryl nitrate: a novel product of the chlorine oxide (OClO) + nitrate radical + M recombination Randall R. Friedl, Stanley P. Sander, and Yuk L. Yung The Journal of Physical Chemistry 1992 96 (19), 7490-7493
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48496
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:13 Aug 2014 20:03
Last Modified:10 Nov 2021 18:32

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