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A study of atom exchange between O_2(^1Δ) and ozone

Anderson, S. M. and Morton, J. and Mauersberger, K. and Yung, Y. L. and DeMore, W. B. (1992) A study of atom exchange between O_2(^1Δ) and ozone. Chemical Physics Letters, 189 (6). pp. 581-585. ISSN 0009-2614. http://resolver.caltech.edu/CaltechAUTHORS:20140813-110851287

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Abstract

It has recently been suggested that isotope exchange between excited bimolecular oxygen and ozone may be partially responsible for the enrichments in stratospheric heavy ozone. To begin evaluating this possibility we have investigated the reaction ^(18)O_2(^1Δ)+^(16)O_3→(labeled ozone products) using a fast-flow reactor and molecular beam mass spectrometry. No reaction was observed, implying that the rate coefficient must be less than 5 × 10^(−16) cm^3/s molecule at 300 K, roughly two orders of magnitude smaller than is required to account for the atmospheric anomalies.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://www.sciencedirect.com/science/article/pii/0009261492852548PublisherArticle
http://dx.doi.org/10.1016/0009-2614(92)85254-8DOIArticle
Alternate Title:A study of atom exchange between O2(1Δ) and ozone
Additional Information:© 1992 Elsevier Science Publishers B.V. Received 27 September 1991; in final form 20 November 1991. Available online 7 February 2002. We would like to thank W.T. Rawlins for stimulating discussions regarding oxygen metastable tactics and R.W. Carr for loan of the microwave equipment.
Record Number:CaltechAUTHORS:20140813-110851287
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140813-110851287
Official Citation:S.M. Anderson, J. Morton, K. Mauersberger, Y.L. Yung, W.B. DeMore, A study of atom exchange between O2(1Δ) and ozone, Chemical Physics Letters, Volume 189, Issue 6, 21 February 1992, Pages 581-585, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(92)85254-8. (http://www.sciencedirect.com/science/article/pii/0009261492852548)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48504
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:13 Aug 2014 19:38
Last Modified:13 Aug 2014 19:38

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