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Bimetallic complexes for polymerization catalysis

Sampson, Jessica and Radlauer, Madalyn and Agapie, Theodor (2014) Bimetallic complexes for polymerization catalysis. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. http://resolver.caltech.edu/CaltechAUTHORS:20140814-130753437

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Abstract

Bimetallic polymn. catalysts based on a rigid terphenyl linker appended with various donors for metal binding have been previously prepd. Access to both meta and para terphenyl linkages allow for variation in metal-metal distance and steric profiles. The chem. of bimetallic complexes supported by phenoxy-imine and bisphenoxy amine ligands has been explored with early and late transition metals. Depending on the nature of the metal and the ligands, these bimetallic catalysts have shown tolerance of amines, polymn. of amino olefins and tacticity control. The mechanism of polymn. of a variety of monomers with these bimetallic catalysts will be discussed.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/fall-2014.htmlOrganizationConference Website
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20140814-130753437
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140814-130753437
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:48568
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:14 Aug 2014 20:25
Last Modified:05 May 2017 20:20

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