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Noninvasive methods for the investigation of ancient Chinese jades: an integrated analytical approach

Casadio, Francesca and Douglas, Janet G. and Faber, Katherine T. (2007) Noninvasive methods for the investigation of ancient Chinese jades: an integrated analytical approach. Analytical and Bioanalytical Chemistry, 387 (3). pp. 791-801. ISSN 1618-2642. doi:10.1007/s00216-006-0684-y. https://resolver.caltech.edu/CaltechAUTHORS:20140908-181320601

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Abstract

This paper reports on an integrated analytical approach for the noninvasive characterization of Chinese nephrite samples, encompassing both geological reference specimens and museum objects. Natural variations induced by cationic substitutions, as well as human-induced alterations such as heating, which both affect color, are the focus of this contribution. Totally noninvasive methods of analysis were used, including X-ray fluorescence spectroscopy, Raman microspectroscopy, visible reflectance spectroscopy and X-ray diffraction; moreover, the feasibility of using a portable Raman spectrometer for the in-field identification of jades has been demonstrated. Fe/Fe+Mg (% p.f.u.) ratios of the jades have been calculated based on hydroxyl stretching Raman bands, which will provide an important addition to similar data that are being collected at major museums in the Western and Eastern hemispheres.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1007/s00216-006-0684-yDOIArticle
http://link.springer.com/article/10.1007%2Fs00216-006-0684-yPublisherArticle
ORCID:
AuthorORCID
Faber, Katherine T.0000-0001-6585-2536
Additional Information:© 2006 Springer. Received: 30 May 2006 / Revised: 5 July 2006 / Accepted: 14 July 2006 / Published online: 16 August 2006. Conservation science research at the Art Institute of Chicago is made possible by a generous grant from the A. W. Mellon Foundation. The Community Associates of the Art Institute are thanked for their support of the microfocus XRF. Elinor Pearlstein and Jay Xu, curators of Asian Art at the Art Institute of Chicago, are also thanked. The assistance of Susie James, Alyson Whitney, Jerry Carsello and Benjamin Meyers for data collection at Northwestern is gratefully acknowledged. X-ray facilities at NU are supported by the MRSEC program of the National Science Foundation (DMR-0076097) of the Materials Research Center of Northwestern University. Wen Guang, Feng Min, Tan Li-ping and Joseph Hotung are thanked for providing reference nephrite samples.
Funders:
Funding AgencyGrant Number
Andrew W. Mellon FoundationUNSPECIFIED
Community Associates of the Art InstituteUNSPECIFIED
NSFDMR-0076097
Subject Keywords:Jade; Nephrite; XRD; Raman spectroscopy; Visible spectrophotometry
Issue or Number:3
DOI:10.1007/s00216-006-0684-y
Record Number:CaltechAUTHORS:20140908-181320601
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140908-181320601
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:49375
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:09 Sep 2014 15:21
Last Modified:10 Nov 2021 18:43

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