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The synthesis of aluminophosphate and germanosilicate LTA using a triquaternary structure directing agent

Schmidt, Joel E. and Zones, Stacey I. and Xie, Dan and Davis, Mark E. (2014) The synthesis of aluminophosphate and germanosilicate LTA using a triquaternary structure directing agent. Microporous and Mesoporous Materials, 200 . pp. 132-139. ISSN 1387-1811. doi:10.1016/j.micromeso.2014.08.051. https://resolver.caltech.edu/CaltechAUTHORS:20140915-074106006

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Abstract

The use of triquaternary organic structure directing agents (OSDAs) for the synthesis of microporous materials is relatively unexplored. Here a triquaternary OSDA prepared by reacting 1,2-dimethylimidazole with 1,3,5-tris(bromomethyl)benzene promotes the formation of LTA in the aluminophosphate or germanosilicate reaction chemistries.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/j.micromeso.2014.08.051DOIArticle
http://www.sciencedirect.com/science/article/pii/S1387181114004855PublisherArticle
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 2014 Elsevier Inc. Received 17 May 2014; Received in revised form 8 August 2014; Accepted 21 August 2014; Available online 1 September 2014. The authors would like to thank Chevron Energy and Technology Company for providing funding for this work. J.E.S. would like to thank the NDSEG for their support through a fellowship. We would also like to thank Son-Jong Hwang for collecting the ^(19)F NMR spectrum.
Funders:
Funding AgencyGrant Number
Chevron Energy and Technology Co.UNSPECIFIED
National Defense Science and Engineering Graduate (NDSEG) FellowshipUNSPECIFIED
Subject Keywords:LTA; ITQ-24; Triquaternary structure directing agents; Germanosilicate; Aluminophosphate
DOI:10.1016/j.micromeso.2014.08.051
Record Number:CaltechAUTHORS:20140915-074106006
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20140915-074106006
Official Citation:Joel E. Schmidt, Stacey I. Zones, Dan Xie, Mark E. Davis, The synthesis of aluminophosphate and germanosilicate LTA using a triquaternary structure directing agent, Microporous and Mesoporous Materials, Volume 200, December 2014, Pages 132-139, ISSN 1387-1811, http://dx.doi.org/10.1016/j.micromeso.2014.08.051. (http://www.sciencedirect.com/science/article/pii/S1387181114004855)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:49681
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:15 Sep 2014 17:33
Last Modified:10 Nov 2021 18:47

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