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Quantitative High-Resolution Gas Chromatography and High-Resolution Gas Chromatography/Mass Spectrometry Analyses of Carbonaceous Fine Aerosol Particles

Mazurek, Monica A. and Simoneit, Bernd R. T. and Cass, Glen R. and Gray, H. Andrew (1987) Quantitative High-Resolution Gas Chromatography and High-Resolution Gas Chromatography/Mass Spectrometry Analyses of Carbonaceous Fine Aerosol Particles. International Journal of Environmental Analytical Chemistry, 29 (1-2). pp. 119-139. ISSN Taylor & Francis. http://resolver.caltech.edu/CaltechAUTHORS:20140915-144241036

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Abstract

Methods have been developed for the quantification of low-microgram levels of the extractable organic matter contained in the atmospheric fine aerosol fraction. Extract quantification is accomplished by computer-assisted high-resolution gas chromatography (HRGC) used in conjunction with a procedural recovery mixture containing perdeuterated compounds of differing polarity and molecular weight. Recovery data for these species indicate that relative volatility rather than functional group classification is the primary factor affecting overall recovery. Routine quality control analysis is performed on a per-sample basis by high-resolution gas chromatography/mass spectrometry (HRGC/MS) for confirmation of the standard components and for identification of procedural contaminants. By the way of illustration, fine aerosol samples have been analyzed from Anaheim. California. The absolute solvent extract yields range from 49 to 346μg of organic carbon, and demonstrate a seasonal variation with winter maximum and summer minimum concentrations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://www.tandfonline.com/doi/abs/10.1080/03067318708078415PublisherArticle
http://dx.doi.org/10.1080/03067318708078415DOIArticle
Additional Information:© 1987 Gordon and Breach, Science Publishers Inc. Received: 9 Jul 1986; in final form September 15 1986. Published online: 19 Dec 2006. We thank Ed Ruth and Gary Taghon for their valuable comments and suggestions. Thanks are also given to Karen Dykes and Celeste Correia for their assistance in the manuscript preparation. Financial support from the Atmospheric Research Section, National Science Foundation (Grants ATM 81-16622, ATM 81-18101 and ATM 85-09184) and from the California Air Resources Board under agreement A1-071-32, is gratefully acknowledged.
Group:Environmental Quality Laboratory
Funders:
Funding AgencyGrant Number
NSFATM 81-16622
NSFATM 81-18101
NSFATM 85-09184
California Air Resources BoardA1-071-32
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Environmental Quality LaboratoryA-197
Record Number:CaltechAUTHORS:20140915-144241036
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20140915-144241036
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:49724
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Sep 2014 17:58
Last Modified:16 Sep 2014 17:58

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