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Terahertz vibration-rotation-tunneling spectroscopy of the propane–water dimer: The ortho-state of a 20cm^(−1) torsion

Lin, Wei and Steyert, David W. and Hlavacek, Nikolaus C. and Mukhopadhyay, Anamika and Page, Ralph H. and Siegel, Peter H. and Saykally, Richard J. (2014) Terahertz vibration-rotation-tunneling spectroscopy of the propane–water dimer: The ortho-state of a 20cm^(−1) torsion. Chemical Physics Letters, 612 . pp. 167-171. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20141023-134521608

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Abstract

We report the detailed characterization of a torsional vibration-rotation-tunneling band of the ortho-state of the propane–water dimer in the spectral region near 20 cm^(−1) (0.6 THz). This work extends the previously reported studies with more than one hundred new transitions included in a combined fit with the 155 previously reported transitions in both the microwave and terahertz regions for this torsional band. More than six hundred transitions have now been recorded in the interval 500 and 810 GHz.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://www.sciencedirect.com/science/article/pii/S0009261414006873PublisherArticle
http://dx.doi.org/10.1016/j.cplett.2014.08.019DOIArticle
ORCID:
AuthorORCID
Siegel, Peter H.0000-0002-2539-4646
Additional Information:© 2014 Elsevier B.V. Received 21 July 2014. In final form 7 August 2014. Available online 14 August 2014. AcknowledgementsThis work was supported by Experimental Physical Chemistry Division of the National Science Foundation under Grant No.1300723 for RJS. This work was supported in part by the U.S. Department of Energy, Office of Science, Office of Workforce Development for Teachers and Scientists (WDTS) under the Visiting Faculty Program (VFP). WL thanks the Welch Foundation for financial support.
Funders:
Funding AgencyGrant Number
NSF1300723
Department of Energy (DOE)UNSPECIFIED
Welch FoundationUNSPECIFIED
Record Number:CaltechAUTHORS:20141023-134521608
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20141023-134521608
Official Citation:Wei Lin, David W. Steyert, Nikolaus C. Hlavacek, Anamika Mukhopadhyay, Ralph H. Page, Peter H. Siegel, Richard J. Saykally, Terahertz vibration-rotation-tunneling spectroscopy of the propane–water dimer: The ortho-state of a 20 cm−1 torsion, Chemical Physics Letters, Volume 612, 18 September 2014, Pages 167-171, ISSN 0009-2614, http://dx.doi.org/10.1016/j.cplett.2014.08.019. (http://www.sciencedirect.com/science/article/pii/S0009261414006873)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:50745
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Oct 2014 23:24
Last Modified:09 Mar 2020 13:19

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