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Secondary organic aerosol 1. Atmospheric chemical mechanism for production of molecular constituents

Griffin, Robert J. and Dabdub, Donald and Seinfeld, John H. (2002) Secondary organic aerosol 1. Atmospheric chemical mechanism for production of molecular constituents. Journal of Geophysical Research D, 107 (D17). Art. No. 4332. ISSN 0148-0227. doi:10.1029/2001JD000541. https://resolver.caltech.edu/CaltechAUTHORS:20141027-143350672

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Abstract

This series of three papers addresses the representation of secondary organic aerosol (SOA) in atmospheric models. SOA forms when gas-phase organic species undergo oxidation, leading to products of sufficiently low vapor pressure that can partition between the gas and aerosol phases. The present paper, part 1, is devoted to the development of a gas-phase atmospheric chemical mechanism designed to represent ozone chemistry as well as formation of individual organic oxidation products that are capable of forming SOA. The ozone chemistry in the mechanism draws upon the recent work of Stockwell et al. [1997] and Jenkin et al. [1997] and SAPRC-97 and SAPRC-99 (available from W.P.L. Carter at http://helium.ucr.edu/~carter/). The mechanism is evaluated in the three-dimensional California Institute of Technology (CIT) model [Meng et al., 1998] by simulating gas-phase concentrations in the South Coast Air Basin (SoCAB) of California over the period 27–29 August 1987. Total predicted concentrations of gas-phase SOA compounds are compared with levels of SOA that have been inferred on the basis of ambient organic aerosol measurements during this period. These predicted concentrations indicate that the total gas-phase potential of SOA-forming compounds can account for observed aerosol concentrations. Part 2 develops a thermodynamic gas–aerosol partitioning module, and part 3 presents a full three-dimensional simulation of gas and aerosol levels in the SoCAB during a 1993 episode.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1029/2001JD000541DOIArticle
http://onlinelibrary.wiley.com/doi/10.1029/2001JD000541/abstractPublisherArticle
ORCID:
AuthorORCID
Seinfeld, John H.0000-0003-1344-4068
Additional Information:Copyright 2002 by the American Geophysical Union. Received 23 February 2001; revised 10 August 2001; accepted 18 December 2001; published 11 September 2002. This work was funded by the United States Environmental Protection Agency under grant R826371-01, by the State of California Air Resources Board under contract 98-314, and by the Electric Power Research Institute. Although the research described in this article has been funded in part by the U. S. Environmental Protection Agency's STAR program through grant R826371-01, it has not been subjected to any EPA review and therefore does not necessarily reflect the views of the Agency, and no official endorsement should be inferred.
Funders:
Funding AgencyGrant Number
Environmental Protection Agency (EPA)R826371-01
California Air Resources Board98-314
Electric Power Research Institute (EPRI)UNSPECIFIED
Subject Keywords:secondary organic aerosol; biogenic aerosol; photooxidation; urban air quality
Issue or Number:D17
Classification Code:0305 Atmospheric Composition and Structure: Aerosols and particles (0345, 4801); 0345 Atmospheric Composition and Structure: Pollution—urban and regional (0305); 0365 Atmospheric Composition and Structure: Troposphere—composition and chemistry
DOI:10.1029/2001JD000541
Record Number:CaltechAUTHORS:20141027-143350672
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20141027-143350672
Official Citation:Griffin, R. J., D. Dabdub, and J. H. Seinfeld, Secondary organic aerosol, 1, Atmospheric chemical mechanism for production of molecular constituents, J. Geophys. Res., 107(D17), 4332, doi:10.1029/2001JD000541, 2002.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:50875
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:27 Oct 2014 21:46
Last Modified:10 Nov 2021 19:02

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