Table A1a. NOAA WP-3D Aircraft Instrumentation for Gas-Phase Measurements Species/Parameter Reference Technique Time Resolution, s Inaccuracy (1 sigma) Imprecision (1 sigma) NO Ryerson et al. [1999] O3-induced chemiluminescence (CL) 1 5% 0.015 ppbv NO2 Ryerson et al. [2000] UV photolysis-CL 1 9% 0.040 ppbv NOy Ryerson et al. [1999] Au converter-CL 1 12% 0.200 ppbv O3 Ryerson et al. [1998] NO-induced CL 1 3% 0.050 ppbv CO Holloway et al. [2000] VUV resonance fluorescence 1 5% 0.500 ppbv CO2 Daube et al. [2002] NDIR absorption 1 0.08 ppmv 0.110 ppmv SO2 Ryerson et al. [1998] Pulsed UV fluorescence 3 10% 0.300 ppbv C2-C10 NMHCs Schauffler et al. [1999] whole air sample/GC-FID 8-30a 5-10% 0.003 ppbv C1-C2 halocarbons Schauffler et al. [1999] whole air sample/GC-MS 8-30a 2-20% <0.050 ppbv C1-C5 alkyl nitrates Schauffler et al. [1999] whole air sample/GC-MS 8-30a 10-20% 0.0002 ppbv isoprene, monoterpenes, CH3CN, oxygenates, and aromatics de Gouw et al. [2003] Proton transfer reaction mass spectrometry (PTRMS) 17 10-20% <0.250 ppbv C2H4 de Gouw et al. [2009] laser photoacoutic absorption spectroscopy (LPAS) 20 10% 0.700 ppbv HCHO Weibring et al. [2007] Difference frequency generation tunable diode laser absorption 1 13% 0.220 ppbv PAN, PPN, PiBN, APAN, MPAN, MoPAN Slusher et al. [2004] I- chemical ionization mass spectrometry (CIMS) 2 30% (100% for MPAN) 0.020 ppbv NO3, N2O5 Dubé et al. [2006] Cavity ring-down spectroscopy (CARDS) 1 20% 0.002 ppbv NH3 Nowak et al. [2007] protonated acetone dimer CIMS 1 25% 0.080 ppbv HNO3 Neuman et al. [2002] SiF5- CIMS 1 15% 0.100 ppbv HO2 + RO2 Eisele and Tanner [1993] NO titration-NO3- CIMS 10 40% 5 x 106 cm-3 H2SO4 Eisele and Tanner [1993] NO3- CIMS 10 30% 1 x 106 cm-3 UV-VIS actinic flux Stark et al. [2007] spectrally resolved radiometry using hemispheric collectors in zenith and nadir 1 15% (30% for jO1D) Visible and IR irradiance Pilewskie et al. [2003] Solar Spectral Flux Radiometer 1 3-5% 0.2% H2O tunable diode laser spectrometry 1 1.0degreeC 0.3degreeC H2O chilled mirror hygrometry 1 1.0degreeC 1.0degreeC aSampling time depends on aircraft altitude.