Penner, Reginald M. and Heben, Michael J. and Longin, Teresa L. and Lewis, Nathan S. (1990) Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry. Science, 250 (4984). pp. 1118-1121. ISSN 0036-8075. doi:10.1126/science.250.4984.1118. https://resolver.caltech.edu/CaltechAUTHORS:20141203-160128178
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Abstract
Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, k_(het), that are two orders of magnitude faster than k_(het) values accessible with any other electrochemical method.
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Additional Information: | © 1990 American Association for the Advancement of Science. 15 August 1990; Accepted 13 September 1990. We acknowledge the Office of Naval Research for support of this work and F. C. Anson and M. J. Weaver for helpful discussions. Contribution no. 8153 from the Division of Chemistry and Chemical Engineering at Caltech. We dedicate this report to George McManis, whose promising scientific career was tragically cut short by his untimely death. | |||||||||
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Issue or Number: | 4984 | |||||||||
DOI: | 10.1126/science.250.4984.1118 | |||||||||
Record Number: | CaltechAUTHORS:20141203-160128178 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141203-160128178 | |||||||||
Official Citation: | Penner, R. M., Heben, M. J., Longin, T. L., & Lewis, N. S. (1990). Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry. Science, 250(4984), 1118-1121. doi: 10.1126/science.250.4984.1118 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 52360 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Joanne McCole | |||||||||
Deposited On: | 04 Dec 2014 20:43 | |||||||||
Last Modified: | 10 Nov 2021 19:25 |
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