Mankad, Neal P. and Peters, Jonas C. (2008) Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph_2BP^(tBu)_2]Cu(η^1-N_2CR_2), [Ph_2BP^(tBu)_2]Cu(CPh_2), and [Ph_2BP^(tBu)_2]Cu–N(CPh_2)(NCPh_2). Chemical Communications, 2008 (9). pp. 1061-1063. ISSN 1359-7345. doi:10.1039/b713687k. https://resolver.caltech.edu/CaltechAUTHORS:20141209-143755965
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Abstract
[Ph_2BP^(tBu)_2]Cu–L complexes react with diazoalkanes to generate structurally unusual η^1-diazoalkane adducts, a terminal carbene, and an η^1-azine adduct.
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| Additional Information: | © 2008 Royal Society of Chemistry. Received 06 Sep 2007, Accepted 14 Dec 2007, First published online 17 Jan 2008. This work was funded by BP (MC2 program) and the NSF (CHE-0132216). N. P. M. is grateful for an NSF Graduate Research Fellowship. J. Christopher Thomas is acknowledged for preliminary reaction screening. John Keith gave useful advice regarding DFT calculations, and Larry Henling provided crystallographic assistance. DFT calculations were done at the Materials and Process Simulation Center at the California Institute of Technology. | |||||||||
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| Issue or Number: | 9 | |||||||||
| DOI: | 10.1039/b713687k | |||||||||
| Record Number: | CaltechAUTHORS:20141209-143755965 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141209-143755965 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 52513 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 09 Dec 2014 22:49 | |||||||||
| Last Modified: | 10 Nov 2021 19:41 |
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