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Reductive trapping of dinitrogen by molybdenum tris anilide to form a dinitrogen anion and chemistries thereof

Cherry, John-Paul F. and Peters, Jonas C. and Cummins, Christopher C. (1999) Reductive trapping of dinitrogen by molybdenum tris anilide to form a dinitrogen anion and chemistries thereof. Abstracts of Papers of the American Chemical Society, 218 . INOR-560. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20141210-095135539

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Abstract

The isolation and characterization of the anoinic dinitrogen complex, [Na][N_2Mo(N[t-Bu]Ar)_3] (Ar=3,5 dimethylaryl) has been accomplished. The capture of dinitrogen also occurs during the formation of (RR'N)_3TiN_2Mo(N[t-Bu]Ar)_3 where R=t-Bu and R'=Ph or R=R'=Me. Activation of small molecules with these dinitrogen complexes has been studied encompassing an array of CS_2 and CO_2 reactions. Elimination of dinitrogen from the anionic complex formed the η^2 complex, (Ar[t-Bu]N)_3Mo(CS_2SiMe_3).


Item Type:Article
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 1999 American Chemical Society.
Record Number:CaltechAUTHORS:20141210-095135539
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20141210-095135539
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:52540
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:10 Dec 2014 18:00
Last Modified:26 Nov 2019 11:15

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