Cherry, John-Paul F. and Peters, Jonas C. and Cummins, Christopher C. (1999) Reductive trapping of dinitrogen by molybdenum tris anilide to form a dinitrogen anion and chemistries thereof. Abstracts of Papers of the American Chemical Society, 218 . INOR-560. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20141210-095135539
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Abstract
The isolation and characterization of the anoinic dinitrogen complex, [Na][N_2Mo(N[t-Bu]Ar)_3] (Ar=3,5 dimethylaryl) has been accomplished. The capture of dinitrogen also occurs during the formation of (RR'N)_3TiN_2Mo(N[t-Bu]Ar)_3 where R=t-Bu and R'=Ph or R=R'=Me. Activation of small molecules with these dinitrogen complexes has been studied encompassing an array of CS_2 and CO_2 reactions. Elimination of dinitrogen from the anionic complex formed the η^2 complex, (Ar[t-Bu]N)_3Mo(CS_2SiMe_3).
Item Type: | Article | ||||
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ORCID: |
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Additional Information: | © 1999 American Chemical Society. | ||||
Record Number: | CaltechAUTHORS:20141210-095135539 | ||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141210-095135539 | ||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
ID Code: | 52540 | ||||
Collection: | CaltechAUTHORS | ||||
Deposited By: | Tony Diaz | ||||
Deposited On: | 10 Dec 2014 18:00 | ||||
Last Modified: | 26 Nov 2019 11:15 |
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