Lu, Connie C. and Peters, Jonas C. (2002) Selective activation of Sp^3 C-H bonds of tertiary amines. Abstracts of Papers of the American Chemical Society, 224 . INOR-561. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20141210-100631418
Full text is not posted in this repository.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20141210-100631418
Abstract
Our group is interested in C-H bond activation by late transition metals supported by the anionic bis(phosphino)borate ligand, Ph_2B(CH_2PPh_2)_2 (abbreviated Ph_2BP_2). In this talk, we focus on the reactivity of the complex [(Ph_2BP_2)Pd(THF)_2][0Tf] (1). Compound 1 reacts with tertiary amines via C-H bond activation to generate a three-membered Pd-N-C metallacycle. The scope of this reaction will be discussed, as well as strategies for futher substrate functionalization.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| ORCID: |
| ||||
| Additional Information: | © 2002 American Chemical Society. | ||||
| Record Number: | CaltechAUTHORS:20141210-100631418 | ||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141210-100631418 | ||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 52544 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | Tony Diaz | ||||
| Deposited On: | 10 Dec 2014 18:15 | ||||
| Last Modified: | 26 Nov 2019 11:15 |
Repository Staff Only: item control page
