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Selective activation of Sp^3 C-H bonds of tertiary amines

Lu, Connie C. and Peters, Jonas C. (2002) Selective activation of Sp^3 C-H bonds of tertiary amines. Abstracts of Papers of the American Chemical Society, 224 . INOR-561. ISSN 0065-7727.

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Our group is interested in C-H bond activation by late transition metals supported by the anionic bis(phosphino)borate ligand, Ph_2B(CH_2PPh_2)_2 (abbreviated Ph_2BP_2). In this talk, we focus on the reactivity of the complex [(Ph_2BP_2)Pd(THF)_2][0Tf] (1). Compound 1 reacts with tertiary amines via C-H bond activation to generate a three-membered Pd-N-C metallacycle. The scope of this reaction will be discussed, as well as strategies for futher substrate functionalization.

Item Type:Article
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2002 American Chemical Society.
Record Number:CaltechAUTHORS:20141210-100631418
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:52544
Deposited By: Tony Diaz
Deposited On:10 Dec 2014 18:15
Last Modified:26 Nov 2019 11:15

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