Cummins, Christopher C. and Odom, Aaron L. and Johnson, Marc J. A. and Peters, Jonas C. and Davis, William M. (1997) Atom-abstraction as a synthetic tool. Abstracts of Papers of the American Chemical Society, 214 . INOR-136. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20141210-102137883
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Abstract
Three-coordinate complexes of formula M(N[R]Ar)_3 (R = C(CD_3)_2CH_3; Ar = 3,5- C_6H_3Me_2) have been found to serve as halogen (M = Ti) and nitrogen or phosphorus (M =Mo) abstraction agents. A variety of reactions have been investigated with the intent of delineating chemistry arising as a consequence of atom-abstraction. As an example, reaction of Mo(N[R]Ar)_3 with N=Mo(S-1 adamantyl)_3 leads to intermetal N-atom transfer via an observable nitrido-bridged intermediate.
| Item Type: | Article | ||||
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| Additional Information: | © 1997 American Chemical Society. | ||||
| Record Number: | CaltechAUTHORS:20141210-102137883 | ||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141210-102137883 | ||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 52546 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | Tony Diaz | ||||
| Deposited On: | 10 Dec 2014 18:34 | ||||
| Last Modified: | 26 Nov 2019 11:15 |
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