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Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Scandium

Min, Endy Y.-J and Bercaw, John E. and Kenward, Alyson L. and Piers, Warren (2014) Bis(η^5-Pentamethylcyclopentadienyl) Complexes of Scandium. In: Inorganic Syntheses. No.36. Wiley , Hoboken, N.J., pp. 42-47. ISBN 9781118744871.

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Use of pentamethylcyclopentadienyl ligands (C_5Me_5) in place of cyclopentadienyl (Cp) provides reactive, but thermally robust monomelic 14-electron scandocene derivatives. A useful starting material for the synthesis of a variety of derivatives of permethylscandocene is the chloride complex. All experiments discussed in this chapter are conducted under argon in a glove box or a high-vacuum line. The chapter describes the procedures for the preparation and properties of bis(η^5-pentamethylcyclopentadienyl) chloroscandium, bis(η^5-pentamethylcyclopentadienyl) methylscandium, bis(η^5-pentamethylcyclopentadienyl) phenylscandium, and bis(η^5-pentamethylcyclopentadienyl)(o-tolyl) scandium.

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Additional Information:© 2014 by John Wiley & Sons, Inc. Published Online: 11 Apr 2014.
Issue or Number:36
Record Number:CaltechAUTHORS:20141215-144354161
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Official Citation:Min, E. Y.-J., Bercaw, J. E., Kenward, A. L. and Piers, W. (2014) Bis(η5-Pentamethylcyclopentadienyl) Complexes of Scandium, in Inorganic Syntheses: Volume 36 (eds G. S. Girolami and A. P. Sattelberger), John Wiley & Sons, Inc., Hoboken, New Jersey. doi: 10.1002/9781118744994.ch09
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:52825
Deposited By: Ruth Sustaita
Deposited On:15 Dec 2014 23:18
Last Modified:03 Oct 2019 07:44

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