Min, Endy Y.-J and Bercaw, John E. and Kenward, Alyson L. and Piers, Warren (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Scandium. In: Inorganic Syntheses. No.36. Wiley , Hoboken, N.J., pp. 42-47. ISBN 9781118744871. https://resolver.caltech.edu/CaltechAUTHORS:20141215-144354161
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Abstract
Use of pentamethylcyclopentadienyl ligands (C₅Me₅) in place of cyclopentadienyl (Cp) provides reactive, but thermally robust monomelic 14-electron scandocene derivatives. A useful starting material for the synthesis of a variety of derivatives of permethylscandocene is the chloride complex. All experiments discussed in this chapter are conducted under argon in a glove box or a high-vacuum line. The chapter describes the procedures for the preparation and properties of bis(η⁵-pentamethylcyclopentadienyl) chloroscandium, bis(η⁵-pentamethylcyclopentadienyl) methylscandium, bis(η⁵-pentamethylcyclopentadienyl) phenylscandium, and bis(η⁵-pentamethylcyclopentadienyl)(o-tolyl) scandium.
| Item Type: | Book Section | ||||||
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| Additional Information: | © 2014 by John Wiley & Sons, Inc. Published Online: 11 Apr 2014. | ||||||
| Subject Keywords: | bis(η5‐pentamethylcyclopentadienyl) chloroscandium; bis(η5‐pentamethylcyclopentadienyl) methylscandium; bis(η5‐pentamethylcyclopentadienyl) phenylscandium; bis(η5‐pentamethylcyclopentadienyl)(o‐tolyl) scandium | ||||||
| Issue or Number: | 36 | ||||||
| DOI: | 10.1002/9781118744994.ch09 | ||||||
| Record Number: | CaltechAUTHORS:20141215-144354161 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20141215-144354161 | ||||||
| Official Citation: | Min, E. Y.-J., Bercaw, J. E., Kenward, A. L. and Piers, W. (2014) Bis(η5-Pentamethylcyclopentadienyl) Complexes of Scandium, in Inorganic Syntheses: Volume 36 (eds G. S. Girolami and A. P. Sattelberger), John Wiley & Sons, Inc., Hoboken, New Jersey. doi: 10.1002/9781118744994.ch09 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 52825 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Ruth Sustaita | ||||||
| Deposited On: | 15 Dec 2014 23:18 | ||||||
| Last Modified: | 10 Nov 2021 19:44 |
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