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Bluebellite and mojaveite, two new minerals from the central Mojave Desert, California, USA

Mills, S. J. and Kampf, A. R. and Christy, A. G. and Housley, R. M. and Rossman, G. R. and Reynolds, R. E. and Marty, J. (2014) Bluebellite and mojaveite, two new minerals from the central Mojave Desert, California, USA. Mineralogical Magazine, 78 (5). pp. 1325-1340. ISSN 0026-461X. http://resolver.caltech.edu/CaltechAUTHORS:20150106-141105881

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Abstract

Bluebellite, Cu_6[I^(5+)O_3(OH)_3](OH)_7Cl and mojaveite, Cu_6[Te^(6+)O_4(OH)_2](OH)_7Cl, are new secondary copper minerals from the Mojave Desert. The type locality for bluebellite is the D shaft, Blue Bell claims, near Baker, San Bernardino County, California, while cotype localities for mojaveite are the E pit at Blue Bell claims and also the Bird Nest drift, Otto Mountain, also near Baker. The two minerals are very similar in their properties. Bluebellite is associated particularly with murdochite, but also with calcite, fluorite, hemimorphite and rarely dioptase in a highly siliceous hornfels. It forms bright bluish-green plates or flakes up to ~20 μm ×20 μm ×5 μm in size that are usually curved. The streak is pale bluish green and the lustre is adamantine, but often appears dull because of surface roughness. It is non-fluorescent. Bluebellite is very soft (Mohs hardness ~1), sectile, has perfect cleavage on {001} and an irregular fracture. The calculated density based on the empirical formula is 4.746 g cm^(−3). Bluebellite is uniaxial (–), with mean refractive index estimated as 1.96 from the Gladstone-Dale relationship. It is pleochroic O (bluish green) >> E (nearly colourless). Electron microprobe analyses gave the empirical formula Cu_(5.82)I_(0.99)Al_(0.02)Si_(0.12)O_(3.11)(OH)_(9.80)Cl_(1.09) based on 14 (O+Cl) a.p.f.u. The Raman spectrum shows strong iodate-related bands at 680, 611 and 254 cm^(−1). Bluebellite is trigonal, space group R3, with the unit-cell parameters: a = 8.3017(5), c = 13.259(1) Å, V = 791.4(1) Å^3 and Z = 3. The eight strongest lines in the powder X-ray diffraction (XRD) pattern are [dobs/Å (I) (hkl)]: 4.427(99)(003), 2.664(35)(211), 2.516(100)(212İ), 2.213(9)(006), 2.103(29)(033,214), 1.899(47)(312,215İ), 1.566(48)(140,217) and 1.479(29)(045,143İ,324). Mojaveite occurs at the Blue Bell claims in direct association with cerussite, chlorargyrite, chrysocolla, hemimorphite, kettnerite, perite, quartz and wulfenite, while at the Bird Nest drift, it is associated with andradite, chrysocolla, cerussite, burckhardtite, galena, goethite, khinite, mcalpineite, thorneite, timroseite, paratimroseite, quartz and wulfenite. It has also been found at the Aga mine, Otto Mountain, with cerussite, chrysocolla, khinite, perite and quartz. Mojaveite occurs as irregular aggregates of greenish-blue plates flattened on {001} and often curved, which rarely show a hexagonal outline, and also occurs as compact balls, from sky blue to medium greenish blue in colour. Aggregates and balls are up to 0.5 mm in size. The streak of mojaveite is pale greenish blue, while the lustre may be adamantine, pearly or dull, and it is non-fluorescent. The Mohs hardness is ~1. It is sectile, with perfect cleavage on {001} and an irregular fracture. The calculated density is 4.886 g cm^(−3), based on the empirical formulae and unit-cell dimensions. Mojaveite is uniaxial (–), with mean refractive index estimated as 1.95 from the Gladstone-Dale relationship. It is pleochroic O (greenish blue) >> E (light greenish blue). The empirical formula for mojaveite, based on 14 (O+Cl) a.p.f.u., is Cu_(5.92)Te_(1.00)Pb_(0.08)Bi_(0.01)O_4(OH)_(8.94)Cl_(1.06).The most intense Raman bands occur at 694, 654 (poorly resolved), 624, 611 and 254 cm^(−1). Mojaveite is trigonal, space group R3, with the unit-cell parameters: a = 8.316(2), c = 13.202(6) Å and V = 790.7(1) Å^3. The eight strongest lines in the powder XRD pattern are [d_(obs/) Å (I) (hkl)]: 4.403(91)(003), 2.672(28)(211), 2.512(100)(212İ), 2.110(27)(033,214), 1.889(34)(312,215İ,223İ), 1.570(39)(404,140,217), 1.481(34)(045,143İ,324) and 1.338(14)(422). Diffraction data could not be refined, but stoichiometries and unit-cell parameters imply that bluebellite and mojaveite are very similar in crystal structure. Structure models that satisfy bond-valence requirements are presented that are based on stackings of brucite-like Cu_6MX_(14) layers, where M = (I or Te) and X = (O, OH and Cl). Bluebellite and mojaveite provide a rare instance of isotypy between an iodate containing I^(5+) with a stereoactive lone electron pair and a tellurate containing Te^(6+) with no lone pair.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1180/minmag.2014.078.5.15DOIArticle
http://minmag.geoscienceworld.org/content/78/5/1325.abstractPublisherArticle
ORCID:
AuthorORCID
Rossman, G. R.0000-0002-4571-6884
Additional Information:© 2014 The Mineralogical Society. Received 6 March 2014; Accepted 5 May 2014; Associate Editor: G. D. Gatta. Two anonymous reviewers are thanked for helpful suggestions which improved the manuscript. Quintin Johnson of Materials Data, Inc., is thanked for conducting the initial structure solution using the RUBY program. Part of this study has been funded by The Ian Potter Foundation grant "tracking tellurium" to SJM which is gratefully acknowledged. The microprobe analyses were supported by a grant to Caltech from the Northern California Mineralogical Association. The XRD analyses were funded by the John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County.
Funders:
Funding AgencyGrant Number
Ian Potter Foundation"tracking tellurium"
Northern California Mineralogical AssociationUNSPECIFIED
John Jago Trelawney EndowmentUNSPECIFIED
Subject Keywords:Bluebellite, mojaveite, new mineral, iodate, tellurate, crystal structure, Raman spectroscopy, Otto Mountain, Blue Bell Claim, California
Record Number:CaltechAUTHORS:20150106-141105881
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150106-141105881
Official Citation:S. J. Mills, A. R. Kampf, A. G. Christy, R. M. Housley, G. R. Rossman, R. E. Reynolds, and J. Marty Bluebellite and mojaveite, two new minerals from the central Mojave Desert, California, USA Mineralogical Magazine, October 2014, v. 78, p. 1325-1340, published online January 2, 2015, doi:10.1180/minmag.2014.078.5.15
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:53223
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Jan 2015 23:06
Last Modified:19 May 2017 15:55

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