Marcus, R. A. (1990) Unimolecular Reactions, Rates and Quantum State Distribution of Products. Philosophical Transactions A: Mathematical, Physical and Engineering Sciences, 332 (1625). pp. 283-296. ISSN 1364-503X . https://resolver.caltech.edu/CaltechAUTHORS:20150107-103454609
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Abstract
Microcanonical rates and products rovibrational quantum state distributions of several unimolecular dissociations, and canonical rates of some bimolecular associations, are discussed from the viewpoint of variational Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The results are compared with the experimental data and with the very useful benchmark theory, phase space theory. A two-transition-state description is discussed for the threshold regions for the products vibrational excitations.
| Item Type: | Article | ||||||
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| Additional Information: | © 1990 The Royal Society. It is a pleasure to acknowledge the support of this research by the National Science Foundation, and helpful discussions with S. J. Klippenstein. | ||||||
| Issue or Number: | 1625 | ||||||
| Record Number: | CaltechAUTHORS:20150107-103454609 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150107-103454609 | ||||||
| Official Citation: | Unimolecular Reactions, Rates and Quantum State Distribution of Products R. A. Marcus Philosophical Transactions: Physical Sciences and Engineering Vol. 332, No. 1625, Intramolecular Motion and Chemical Reaction (Aug. 15, 1990) , pp. 283-296 Published by: The Royal Society Stable URL: http://www.jstor.org/stable/76759 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 53266 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 07 Jan 2015 20:32 | ||||||
| Last Modified: | 22 Nov 2019 09:58 |
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