Fukuto, M. and Heilmann, R. K. and Pershan, P. S. and Yu, S. M. and Soto, C. M. and Tirrell, D. A. (2002) Confinement-induced order of tethered alkyl chains at the water/vapor interface. Physical Review E, 66 (1). Art. No. 010601~R!. ISSN 1539-3755. doi:10.1103/PhysRevE.66.010601. https://resolver.caltech.edu/CaltechAUTHORS:FUKpre2003
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Abstract
Packing of tethered alkyl chains in Langmuir monolayers of a hairy-rod polypeptide poly[γ-4-(n-hexadecyloxy)benzyl α,L-glutamate] on water has been studied by x-ray scattering measurements at room temperature. The rods lie parallel to the surface while the alkyl side chains segregate toward the vapor. Results indicate that the herringbone order of the alkyl chains is established initially by one-dimensionally confined chains between aligned rods and grows laterally with compression.
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| Additional Information: | © 2003 American Physical Society. (Received 9 November 2001; published 23 July 2002) The Harvard contribution to this work was supported by Grant No. NSF-DMR-01-24936. D.T. acknowledges support by Grant No. NSF-DMR-01-10437. NSLS at Brookhaven National Laboratory is supported by No. DE-AC02-76CH00016. | |||||||||
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| Issue or Number: | 1 | |||||||||
| Classification Code: | PACS number~s!: 68.18.2g, 61.66.Hq, 61.10.Eq, 61.10.Kw | |||||||||
| DOI: | 10.1103/PhysRevE.66.010601 | |||||||||
| Record Number: | CaltechAUTHORS:FUKpre2003 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:FUKpre2003 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 53347 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Anne Hormann | |||||||||
| Deposited On: | 07 Feb 2015 19:31 | |||||||||
| Last Modified: | 10 Nov 2021 20:00 |
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