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Reactivities of monomers towards the 1-phenylethyl radical

Bevington, J. C. and Cywar, D. A. and Huckerby, T. N. and Senogles, E. and Tirrell, D. A. (1990) Reactivities of monomers towards the 1-phenylethyl radical. European Polymer Journal, 26 (1). pp. 41-46. ISSN 0014-3057. https://resolver.caltech.edu/CaltechAUTHORS:BEVepj1990

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Abstract

The reactivities of styrene, methyl acrylate, methyl methacrylate, methyl isopropenyl ketone, methyl vinyl ketone and 2-vinylpyridine towards the 1-phenylethyl radical at 100° have been compared using acenaphthylene as the reference monomer. Binary copolymerizations with acenaphthylene were initiated by 1,1′[^(13)C]azobis-1,1′-phenylethane; ^(13)C-NMR spectroscopy was used to compare the numbers of initiator fragments attached to the two types of monomeric units in each of the various copolymers. The relative reactivities of the monomers towards the initiating radical match their relative reactivities towards the polystyrene radical, as deduced from monomer reactivity ratios for copolymerizations with styrene.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0014-3057(90)90095-LDOIArticle
http://www.sciencedirect.com/science/article/pii/001430579090095LPublisherArticle
ORCID:
AuthorORCID
Tirrell, D. A.0000-0003-3175-4596
Additional Information:Copyright © 1990 Elsevier. (Received 14 March 1989)
Issue or Number:1
Record Number:CaltechAUTHORS:BEVepj1990
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:BEVepj1990
Official Citation:J.C. Bevington, D.A. Cywar, T.N. Huckerby, E. Senogles, D.A. Tirrell, Reactivities of monomers towards the 1-phenylethyl radical, European Polymer Journal, Volume 26, Issue 1, 1990, Pages 41-46, ISSN 0014-3057, http://dx.doi.org/10.1016/0014-3057(90)90095-L. (http://www.sciencedirect.com/science/article/pii/001430579090095L)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:53528
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:22 Jan 2015 21:38
Last Modified:03 Oct 2019 07:50

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