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A method for the determination of the relative reactivities of monomers towards the 1-phenylethyl radical

Bevington, J. C. and Cywar, D. A. and Huckerby, T. N. and Senogles, E. and Tirrell, D. A. (1988) A method for the determination of the relative reactivities of monomers towards the 1-phenylethyl radical. European Polymer Journal, 24 (7). pp. 699-702. ISSN 0014-3057. http://resolver.caltech.edu/CaltechAUTHORS:BEVepj1988

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Abstract

Several monomers have been polymerized using 1,1′-azobis(1-phenyl [1-^(13)C] ethane as initiator; the initiator fragments incorporated in the polymers have been examined by ^(13)C-NMR. The chemical shift for the enriched site in the end-group depends upon the nature of the attached monomeric unit. It is concluded that acenaphthylene is suitable as a reference monomer in comparisons of the reactivities of monomers towards the 1-phenylethyl radical (regarded as a model for the polystyrene radical) by consideration of end-groups in copolymers.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0014-3057(88)90038-9DOIArticle
http://www.sciencedirect.com/science/article/pii/0014305788900389PublisherArticle
ORCID:
AuthorORCID
Tirrell, D. A.0000-0003-3175-4596
Additional Information:Copyright © 1988 Pergamon Press. (Received 14 April 1988)
Record Number:CaltechAUTHORS:BEVepj1988
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:BEVepj1988
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:53538
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:10 Jan 2015 13:53
Last Modified:11 Jan 2015 03:32

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