Bevington, J. C. and Cywar, D. A. and Huckerby, T. N. and Senogles, E. and Tirrell, D. A. (1988) A method for the determination of the relative reactivities of monomers towards the 1-phenylethyl radical. European Polymer Journal, 24 (7). pp. 699-702. ISSN 0014-3057. http://resolver.caltech.edu/CaltechAUTHORS:BEVepj1988
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Abstract
Several monomers have been polymerized using 1,1′-azobis(1-phenyl [1-^(13)C] ethane as initiator; the initiator fragments incorporated in the polymers have been examined by ^(13)C-NMR. The chemical shift for the enriched site in the end-group depends upon the nature of the attached monomeric unit. It is concluded that acenaphthylene is suitable as a reference monomer in comparisons of the reactivities of monomers towards the 1-phenylethyl radical (regarded as a model for the polystyrene radical) by consideration of end-groups in copolymers.
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| Additional Information: | Copyright © 1988 Pergamon Press. (Received 14 April 1988) | |||||||||
| Record Number: | CaltechAUTHORS:BEVepj1988 | |||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:BEVepj1988 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 53538 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Anne Hormann | |||||||||
| Deposited On: | 10 Jan 2015 13:53 | |||||||||
| Last Modified: | 11 Jan 2015 03:32 |
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