Jones, Sharon A. and Tirrell, David A. (1986) Model copolymerization reactions. Evidence against participation of a donor-acceptor complex in reactions of the 1-butyl radical with N-phenylmaleimide and 2-chloroethyl vinyl ether. Macromolecules, 19 (7). pp. 2080-2082. ISSN 0024-9297. doi:10.1021/ja507849b10.1021/ma00161a052. https://resolver.caltech.edu/CaltechAUTHORS:JONm1986
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Abstract
The participation of electron donor-acceptor (EDA) complexes in alternating radical copolymerizations has been debated for nearly 40 years. It has been suggested that some alternating copolymerizations may not be copolymerizations at all but instead may proceed via successive concerted additions of 1: 1 comonomer complexes (2) to growing polymeric radicals (1). This is an intriguing idea and, if correct, would explain not only the alternating copolymer structure but also certain kinetic features of alternating copolymerization.
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| Additional Information: | © 1986 American Chemical Society. Received December 31, 1985. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this work. Support of our research by a Presidential Young Investigator Award of the National Science Foundation (to D.A.T.) is also gratefully acknowledged. NMR spectra were recorded in the University of Massachusetts NMR Laboratory, which is supported in part by the NSF Materials Research Laboratory at the University. Registry No. NPM, 941-69-5; CEVE, 110-75-8; BuHgBr, 17774-02-6; 2-butyl-N-phenylsuccinimide, 102651-46-7; 1-butyl radical, 2492-36-6. | |||||||||
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| Issue or Number: | 7 | |||||||||
| DOI: | 10.1021/ja507849b10.1021/ma00161a052 | |||||||||
| Record Number: | CaltechAUTHORS:JONm1986 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:JONm1986 | |||||||||
| Official Citation: | Model copolymerization reactions. Evidence against participation of a donor-acceptor complex in reactions of the 1-butyl radical with N-phenylmaleimide and 2-chloroethyl vinyl ether Sharon A. Jones and David A. Tirrell Macromolecules 1986 19 (7), 2080-2082 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 53599 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Anne Hormann | |||||||||
| Deposited On: | 22 Jan 2015 00:20 | |||||||||
| Last Modified: | 10 Nov 2021 20:04 |
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