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Model copolymerization reactions. Evidence against participation of a donor-acceptor complex in reactions of the 1-butyl radical with N-phenylmaleimide and 2-chloroethyl vinyl ether

Jones, Sharon A. and Tirrell, David A. (1986) Model copolymerization reactions. Evidence against participation of a donor-acceptor complex in reactions of the 1-butyl radical with N-phenylmaleimide and 2-chloroethyl vinyl ether. Macromolecules, 19 (7). pp. 2080-2082. ISSN 0024-9297. http://resolver.caltech.edu/CaltechAUTHORS:20141015-105804358CaltechAUTHORS:JONm1986

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Abstract

The participation of electron donor-acceptor (EDA) complexes in alternating radical copolymerizations has been debated for nearly 40 years. It has been suggested that some alternating copolymerizations may not be copolymerizations at all but instead may proceed via successive concerted additions of 1: 1 comonomer complexes (2) to growing polymeric radicals (1). This is an intriguing idea and, if correct, would explain not only the alternating copolymer structure but also certain kinetic features of alternating copolymerization.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja507849b10.1021/ma00161a052DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ma00161a052PublisherArticle
ORCID:
AuthorORCID
Tirrell, David A.0000-0003-3175-4596
Additional Information:© 1986 American Chemical Society. Received December 31, 1985. Acknowledgment is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this work. Support of our research by a Presidential Young Investigator Award of the National Science Foundation (to D.A.T.) is also gratefully acknowledged. NMR spectra were recorded in the University of Massachusetts NMR Laboratory, which is supported in part by the NSF Materials Research Laboratory at the University. Registry No. NPM, 941-69-5; CEVE, 110-75-8; BuHgBr, 17774-02-6; 2-butyl-N-phenylsuccinimide, 102651-46-7; 1-butyl radical, 2492-36-6.
Funders:
Funding AgencyGrant Number
American Chemical Society Petroleum Research FundUNSPECIFIED
NSFUNSPECIFIED
Record Number:CaltechAUTHORS:JONm1986
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20141015-105804358CaltechAUTHORS:JONm1986
Official Citation:Model copolymerization reactions. Evidence against participation of a donor-acceptor complex in reactions of the 1-butyl radical with N-phenylmaleimide and 2-chloroethyl vinyl ether Sharon A. Jones and David A. Tirrell Macromolecules 1986 19 (7), 2080-2082
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ID Code:53599
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:22 Jan 2015 00:20
Last Modified:22 Jan 2015 00:20

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