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Solar Fuels: Approaches to Catalytic Hydrogen Evolution

Dempsey, J. L. and Winkler, J. R. and Gray, H. B. (2013) Solar Fuels: Approaches to Catalytic Hydrogen Evolution. In: Comprehensive Inorganic Chemistry II. Elsevier , Amsterdam, pp. 553-565. ISBN 978-0-08-096529-1. http://resolver.caltech.edu/CaltechAUTHORS:20150202-083557905

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Abstract

In response to political and environmental motivations to develop alternative energy resources, researchers have taken a variety of approaches to develop solar energy conversion technologies. Solar fuel production is an area of enormous promise where, in analogy to natural photosynthesis, sunlight drives the conversion of energy-poor molecules (H_2O and CO_2) to energy-rich ones (O_2, H_2, and (CH_2O)_n). To realize a solar-driven water splitting device based on earth-abundant materials, new chemistry is needed, including materials for light harvesting and electrocatalysts for fuel production. In this chapter, we focus on molecular hydrogen production catalysts capable of evolving H_2 at low overpotentials. Recent synthetic advances in catalyst design, detailed electrochemical and photochemical studies, and developments in mechanistic understandings are covered.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/B978-0-08-097774-4.00806-8DOIArticle
http://www.sciencedirect.com/science/article/pii/B9780080977744008068PublisherArticle
ORCID:
AuthorORCID
Winkler, J. R.0000-0002-4453-9716
Additional Information:© 2013 Elsevier Ltd. Available online 23 July 2013; Reviewed 26 November 2014. This work was supported by NSF Center for Chemical Innovation (Powering the Planet, CHE-0947829), the Arnold and Mabel Beckman Foundation, and CCSER (Gordon and Betty Moore Foundation). J.L.D. was supported by an NSF Graduate Research Fellowship.
Group:CCI Solar Fuels
Funders:
Funding AgencyGrant Number
NSFCHE-0947829
Arnold and Mabel Beckman FoundationUNSPECIFIED
CCSERUNSPECIFIED
Gordon and Betty Moore FoundationUNSPECIFIED
NSF Graduate Research FellowshipUNSPECIFIED
Subject Keywords:Catalysis; Cobaloxime; Hydrogen; Molecular catalysts; Solar energy; Solar fuel
Record Number:CaltechAUTHORS:20150202-083557905
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150202-083557905
Official Citation:J.L. Dempsey, J.R. Winkler and H.B. Gray, 8.15 - Solar Fuels: Approaches to Catalytic Hydrogen Evolution, In Comprehensive Inorganic Chemistry II (Second Edition), edited by Jan ReedijkKenneth Poeppelmeier, Elsevier, Amsterdam, 2013, Pages 553-565, ISBN 9780080965291, http://dx.doi.org/10.1016/B978-0-08-097774-4.00806-8. (http://www.sciencedirect.com/science/article/pii/B9780080977744008068)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:54276
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Feb 2015 17:40
Last Modified:16 Sep 2017 00:05

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