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Preparation and Characterization of a Series of Poly[oxy-1(ω-bromoalkyl)ethylene]s

Wicks, Douglas A. and Tirrell, David A. (1989) Preparation and Characterization of a Series of Poly[oxy-1(ω-bromoalkyl)ethylene]s. Makromolekulare Chemie, 190 (9). pp. 2019-2030. ISSN 0025-116X. http://resolver.caltech.edu/CaltechAUTHORS:20150209-154900412

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Abstract

2-Bromoethyloxirane (2 b), 3-bromopropyloxirane (2 c) and 4-bromobutyloxirane (2 d) were prepared by epoxidation of the corresponding bromoalkenes. Treatment of the oxiranes with a triethylaluminium/acetylacetone/water mixture afforded the polyethers 3 b - d in good yield as tacky, white elastomers. Substitution of bromide by benzoate ion established essentially equal reactivities for the three polymers; each was substantially more reactive than any of the halogenated polyether elastomers available heretofore.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/macp.1989.021900902DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/macp.1989.021900902/abstractPublisherArticle
ORCID:
AuthorORCID
Tirrell, David A.0000-0003-3175-4596
Additional Information:This paper is dedicated to Professor Paul Rempp on the occasion of his sixtieth birthday, with best personal regards. Issue published online: 12 MAR 2003. Article first published online: 12 MAR 2003. Manuscript Received: 25 AUG 1988. This work was supported by a Presidential Young Investigator Award of the National Science Foundation. NMR spectra were recorded in the University of Massachusetts NMR Laboratory, which is supported in part by the NSF Materials Research Laboratory at the University.
Funders:
Funding AgencyGrant Number
NSF Presidential Young Investigator AwardUNSPECIFIED
NSF Materials Research Laboratory at the University of MassachusettsUNSPECIFIED
Record Number:CaltechAUTHORS:20150209-154900412
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150209-154900412
Official Citation: mer Science & Technology General > Die Makromolekulare Chemie > Vol 190 Issue 9 > Abstract JOURNAL TOOLS Get New Content Alerts Get RSS feed Save to My Profile Get Sample Copy Recommend to Your Librarian JOURNAL MENU Journal Home FIND ISSUES Current Issue All Issues Virtual Issues FIND ARTICLES Early View Most Accessed Reviews GET ACCESS Subscribe / Renew FOR CONTRIBUTORS Submit an Article Author Guidelines OnlineOpen ABOUT THIS JOURNAL Editorial Board Contact Advertise News Overview SPECIAL FEATURES Macromolecular Journals Talents, Trends and Highlights Special Series - Functional Polymers Editorials Macro Awards Materials Views Materials Views China Cover Picture Gallery Maximise the impact of your research with Wiley's free author promotional toolkit Article Preparation and characterization of a series of poly[oxy-1-(ω-bromoalkyl)ethylene]s† Douglas A. Wicks and David A. Tirrell* Article first published online: 12 MAR 2003 DOI: 10.1002/macp.1989.021900902 © 1989 Hüthig & Wepf Verlag, Basel Issue Die Makromolekulare Chemie Die Makromolekulare Chemie Volume 190, Issue 9, pages 2019–2030, September 1989 Additional Information(Show All) How to CiteAuthor InformationPublication History How to Cite Wicks, D. A. and Tirrell, D. A. (1989), Preparation and characterization of a series of poly[oxy-1-(ω-bromoalkyl)ethylene]s. Makromol. Chem., 190: 2019–2030. doi: 10.1002/macp.1989.021900902
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ID Code:54589
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:17 Mar 2015 17:00
Last Modified:17 Mar 2015 17:00

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