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Model Copolymerization Reactions. Evidence Against Participation of a Donor-Acceptor Complex in Reactions of the 1-Butyl Radical with N-Phenylmaleimide and Styrene

Jones, Sharon A. and Tirrell, David A. (1987) Model Copolymerization Reactions. Evidence Against Participation of a Donor-Acceptor Complex in Reactions of the 1-Butyl Radical with N-Phenylmaleimide and Styrene. Journal of Polymer Science Part A: Polymer Chemistry, 25 (11). pp. 3177-3180. ISSN 0887-624X. https://resolver.caltech.edu/CaltechAUTHORS:20150209-161219561

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Abstract

The participation of electron donor-acceptor (EDA) complexes in radical copolymerizations has been the subject of hundreds of research papers? Complex participation has been invoked to explain the formation of alternating copolymer, as well as the variations in overall copolymerization rate with changes in temperature, solvent, or monomer concentration, that are frequently observed in copolymerizations of donor (D) and acceptor (A) olefin. Most recently, Olson and Butler have suggested that complex participation might also be required to explain the stereochemistry, or the regiochemistry, of certain radical copolymerizations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/pola.1987.080251120DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/pola.1987.080251120/abstractPublisherArticle
ORCID:
AuthorORCID
Tirrell, David A.0000-0003-3175-4596
Additional Information:© 1987 John Wiley & Sons. Received July 18, 1986; Accepted December 8, 1986.
Issue or Number:11
Record Number:CaltechAUTHORS:20150209-161219561
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150209-161219561
Official Citation:Jones, S. A. and Tirrell, D. A. (1987), Model copolymerization reactions: Evidence against participation of a donor–acceptor complex in reactions of the l-butyl radical with N-phenylmaleimide and styrene. J. Polym. Sci. A Polym. Chem., 25: 3177–3180. doi: 10.1002/pola.1987.080251120
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:54601
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:13 Feb 2015 15:07
Last Modified:03 Oct 2019 07:59

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