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Triptycene Structure-Directing Agents in Aluminophosphate Synthesis

Boal, Ben W. and Zones, Stacey I. and Davis, Mark E. (2015) Triptycene Structure-Directing Agents in Aluminophosphate Synthesis. Microporous and Mesoporous Materials, 208 . pp. 203-211. ISSN 1387-1811. doi:10.1016/j.micromeso.2015.01.045. https://resolver.caltech.edu/CaltechAUTHORS:20150217-083232800

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Abstract

The synthesis of aluminophosphates is investigated using a number of triptycene-based organic structure-directing agents (OSDA). These OSDAs are designed to synthesize extra-large pore and/or large cavity-containing molecular sieves. Starting from the hydrophobic triptycene molecule, OSDAs are prepared by introducing three amine-based centers that can be charged either by protonation in the acidic aluminophosphate reaction media or through quaternization. VPI-5 is synthesized using these tripytycene OSDAs, and the OSDAs are occluded inside the pores. This synthesis marks the first time VPI-5 has been made as a single phase with an OSDA occluded inside the framework of the as-made material that is not removed by simple washing with water or other solvents. Additionally, several other aluminophosphates with unknown structures are synthesized using these new OSDAs.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/j.micromeso.2015.01.045DOIArticle
http://www.sciencedirect.com/science/article/pii/S1387181115000633PublisherArticle
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 2015 Elsevier Inc. Received Date: 24 September 2014; Revised Date: 26 January 2015; Accepted Date: 27 January 2015; Available online 7 February 2015. This work was financially supported by the Chevron Energy Technology Company. The authors would like to thank Dr. Son-Jong Hwang for solid state NMR assistance.
Funders:
Funding AgencyGrant Number
Chevron Energy Technology CompanyUNSPECIFIED
DOI:10.1016/j.micromeso.2015.01.045
Record Number:CaltechAUTHORS:20150217-083232800
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150217-083232800
Official Citation:Ben W. Boal, Stacey I. Zones, Mark E. Davis, Triptycene structure-directing agents in aluminophosphate synthesis, Microporous and Mesoporous Materials, Volume 208, 15 May 2015, Pages 203-211, ISSN 1387-1811, http://dx.doi.org/10.1016/j.micromeso.2015.01.045. (http://www.sciencedirect.com/science/article/pii/S1387181115000633)February 2015, ISSN 1387-1811, http://dx.doi.org/10.1016/j.micromeso.2015.01.045. (http://www.sciencedirect.com/science/article/pii/S1387181115000633)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:54856
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:17 Feb 2015 18:18
Last Modified:10 Nov 2021 20:38

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