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DFT Study of Oxygen Reduction Reaction on Os/Pt Core−Shell Catalysts Validated by Electrochemical Experiment

Tsai, Ho-Cheng and Hsieh, Yu-Chi and Yu, Ted H. and Lee, Yi-Juei and Wu, Yue-Han and Merinov, Boris V. and Wu, Pu-Wei and Chen, San-Yuan and Adzic, Radoslav R. and Goddard, William A., III (2015) DFT Study of Oxygen Reduction Reaction on Os/Pt Core−Shell Catalysts Validated by Electrochemical Experiment. ACS Catalysis, 5 (3). pp. 1568-1580. ISSN 2155-5435. https://resolver.caltech.edu/CaltechAUTHORS:20150217-103925807

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Abstract

Proton exchange membrane fuel cells (PEMFCs) have attracted much attention as an alternative source of energy with a number of advantages, including high efficiency, sustainability, and environmentally friendly operation. However, the low kinetics of the oxygen reduction reaction (ORR) restricts the performance of PEMFCs. Various types of catalysts have been developed to improve the ORR efficiency, but this problem still needs further investigations and improvements. In this paper, we propose advanced Os/Pt core–shell catalysts based on our previous study on segregation of both bare surfaces and surfaces exposed to ORR adsorbates, and we evaluate the catalytic activity of the proposed materials by density functional theory (DFT). Quantum mechanics was applied to calculate binding energies of ORR species and reaction energy barriers on Os/Pt core–shell catalysts. Our calculations predict a much better catalytic activity of the Os/Pt system than that of pure Pt. We find that the ligand effect of the Os substrate is more important than the lattice compression strain effect. To validate our DFT prediction, we demonstrate the fabrication of Os/Pt core–shell nanoparticles using the underpotential deposition (UPD) technique and succeeding galvanic displacement reaction between the Pt ions and Cu-coated Os nanoparticles. The Os/Pt/C samples were evaluated for electrocatalytic activities toward the ORR in acidic electrolytes. The samples with two consecutive UPD-displacement reaction cycles show 3.5 to 5 times better ORR activities as compared to those of commercially available Pt/C. Our results show good agreement between the computational predictions and electrochemical experimental data for the Os/Pt core–shell ORR catalysts.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/cs501020aDOIArticle
http://pubs.acs.org/doi/abs/10.1021/cs501020aPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/cs501020aRelated ItemSupporting Information
ORCID:
AuthorORCID
Yu, Ted H.0000-0003-3202-0981
Merinov, Boris V.0000-0002-2783-4262
Goddard, William A., III0000-0003-0097-5716
Additional Information:© 2015 American Chemical Society. Received: July 16, 2014. Revised: January 15, 2015. Publication Date (Web): January 22, 2015. This work was supported by Caltech and Taiwan Energy Exchange (CTEE) collaborative program funded by the National Science Council of Taiwan (grant NSC 103-3113-P-008-001) and partially by the National Science Foundation (grant CBET-1067848, Caltech). The work performed at Brookhaven National Laboratory was supported by the U.S. Department of Energy under contract DE-AC02-98CH10886. The facilities of the Materials and Process Simulation Center used in this study were established with grants from DURIP-ONR, DURIP-ARO, and NSF-CSEM.
Funders:
Funding AgencyGrant Number
Caltech Taiwan Energy ExchangeUNSPECIFIED
National Science Council (Taipei)NSC 103-3113-P- 008-001
NSFCBET-1067848
CaltechUNSPECIFIED
Department of Energy (DOE)DE-AC02-98CH10886
Office of Naval Research (ONR)UNSPECIFIED
Army Research Office (ARO)UNSPECIFIED
Issue or Number:3
Record Number:CaltechAUTHORS:20150217-103925807
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150217-103925807
Official Citation:DFT Study of Oxygen Reduction Reaction on Os/Pt Core–Shell Catalysts Validated by Electrochemical Experiment Ho-Cheng Tsai, Yu-Chi Hsieh, Ted H. Yu, Yi-Juei Lee, Yue-Han Wu, Boris V. Merinov, Pu-Wei Wu, San-Yuan Chen, Radoslav R. Adzic, and William A. Goddard, III ACS Catalysis 2015 5 (3), 1568-1580 DOI: 10.1021/cs501020a
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:54867
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:17 Feb 2015 22:26
Last Modified:03 Oct 2019 08:01

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