Marcus, R. A. (2005) Micelle-enhanced dissociation of a Ru cation/DNA complex. Journal of Physical Chemistry B, 109 (45). pp. 21419-21424. ISSN 1520-6106. doi:10.1021/jp051988s. https://resolver.caltech.edu/CaltechAUTHORS:20150316-131449116
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Abstract
Anionic surfactant monomers have a large catalytic effect on the dissociation rate constant of a Ru_2^(4+)−DNA complex, an effect further enhanced upon exceeding the critical micelle concentration. Electrostatic estimates are made of this effect, the effect of salt and temperature on the binding constant, and of the binding constant itself. The effects are compared with the experiment, and the calculated salt effect on the binding constant is compared with condensation theory. The results indicate that the catalytic effect is primarily nonelectrostatic (hydrophobic) in nature.
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| Additional Information: | © 2005 American Chemical Society. Received: April 17, 2005; In Final Form: June 22, 2005. Published on Web August 9, 2005. It is a pleasure to thank Professor Bengt Nordén for calling this area to my attention and for his helpful comments. I am particularly pleased to contribute to this special issue in honor of Prof. Irwin Oppenheim. The research was supported by the Office of Naval Research and the National Science Foundation. | |||||||||
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| Issue or Number: | 45 | |||||||||
| DOI: | 10.1021/jp051988s | |||||||||
| Record Number: | CaltechAUTHORS:20150316-131449116 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150316-131449116 | |||||||||
| Official Citation: | Micelle-Enhanced Dissociation of a Ru Cation/DNA Complex R. A. Marcus The Journal of Physical Chemistry B 2005 109 (45), 21419-21424 DOI: 10.1021/jp051988s | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 55795 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 16 Mar 2015 21:17 | |||||||||
| Last Modified: | 10 Nov 2021 20:50 |
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