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Pyridine-derived dinuclear copper complexes: Synthesis, structure, characterization, and reactivity with small molecules

Ziegler, Micah S. and Davenport, Timothy C. and Tilley, T. Don (2014) Pyridine-derived dinuclear copper complexes: Synthesis, structure, characterization, and reactivity with small molecules. Abstracts of Papers of the American Chemical Society, 248 . 1072-INOR. ISSN 0065-7727. http://resolver.caltech.edu/CaltechAUTHORS:20150324-082218662

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Abstract

Metal-metal distances in bimetallic complexes play an important role in modulating reactivity. However, many dinucleating ligands predetermine an intermetallic distance with the incorporation of a rigid bridging unit that bonds to both metal centers. To investigate the influence of ligand flexibility on the reactivity of dinuclear transition metal complexes, a flexible, robust, pyridine-derived ligand framework that supports a range of metal-metal distances was synthesized. Using this ligand, a dinuclear copper(I) complex has been synthesized and characterized in soln. and the solid state, revealing the ligand's flexible geometry and the metals' coordinative lability. The complex's reactivity with small mols., including oxygen and carbon dioxide, has also been investigated.


Item Type:Article
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http://www.acs.org/content/acs/en/meetings/fall-2014.htmlOrganizationConference Website
ORCID:
AuthorORCID
Tilley, T. Don0000-0002-6671-9099
Additional Information:© 2014 American Chemical Society.
Record Number:CaltechAUTHORS:20150324-082218662
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20150324-082218662
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:55999
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:24 Mar 2015 15:40
Last Modified:19 May 2017 22:43

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