Shih, J. S. and Brandt, J. F. and Zussman, M. P. and Tirrell, D. A. (1982) Poly[(2-chloroethyl)oxirane], poly[(3-chloropropyl)-oxirane] and poly[(4-chlorobutyl)oxirane]: New polyether elastomers of improved chemical reactivity. Journal of Polymer Science: Polymer Chemistry Edition, 20 (10). pp. 2839-2849. ISSN 0360-6376. doi:10.1002/pol.1982.170201010. https://resolver.caltech.edu/CaltechAUTHORS:SHIHjpc82
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Abstract
(2-Chloroethyl)oxirane, (3-chloropropyl)oxirane, and (4-chlorobutyl)oxirane were prepared from the corresponding alkenols and polymerized using a triethylaluminum-water-acetylacetone initiator system. Copolymerizations with propylene oxide and epichlorohydrin were also accomplished; the copolymerization activities of the (chloroalkyl)oxiranes were similar to the activity of epichlorohydrin. Poly[(2-chloroethyl)oxirane], poly[(3-chloropropyl)oxirane], and poly[(4-chlorobutyl)oxirane] exhibit elastomeric properties and are highly reactive in nucleophilic substitution reactions.
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| Additional Information: | © 1982 John Wiley & Sons. Received February 22, 1982; Accepted April 23, 1982. It is a pleasure to acknowledge the following support: an Arco Graduate Research Fellowship to M. P. Zussman, an Alfred P. Sloan Research Fellowship to D. A. Tirrell, and a grant from the Polymers Program of the National Science Foundation (DMR 80-01629). The Bruker WM-300 spectrometer was purchased with the help of a grant from the National Institutes of Health (NIGMS-GM27930-01). | ||||||||||
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| Issue or Number: | 10 | ||||||||||
| DOI: | 10.1002/pol.1982.170201010 | ||||||||||
| Record Number: | CaltechAUTHORS:SHIHjpc82 | ||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:SHIHjpc82 | ||||||||||
| Official Citation: | Shih, J. S., Brandt, J. F., Zussman, M. P. and Tirrell, D. A. (1982), Poly[(2-chloroethyl)oxirane], poly[(3-chloropropyl)-oxirane] and poly[(4-chlorobutyl)oxirane]: New polyether elastomers of improved chemical reactivity. J. Polym. Sci. Polym. Chem. Ed., 20: 2839–2849. doi: 10.1002/pol.1982.170201010 | ||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
| ID Code: | 56123 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Anne Hormann | ||||||||||
| Deposited On: | 27 Mar 2015 23:17 | ||||||||||
| Last Modified: | 10 Nov 2021 20:54 |
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