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Comments on the Role of Molecular Genetics in Polymer Materials Science

Fournier, Maurille J. and Mason, Thomas L. and Tirrell, David A. (1991) Comments on the Role of Molecular Genetics in Polymer Materials Science. In: Materials synthesis based on biological processes : symposium held November 27-29, 1990, Boston, Massachusetts, U.S.A. Materials Research Society Symposia Proceedings. No.218. Materials Research Society , Pittsburgh, PA, pp. 45-48. ISBN 1558991107. https://resolver.caltech.edu/CaltechAUTHORS:20150326-114459002

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Abstract

The most fundamental goal of the synthetic chemist is control of molecular architecture. With respect to small molecules (i.e., those of molecular weight less than a few thousand), this means absolute control of chemical connectivity and stereochemistry – complete specification of molecular structure. But in macromolecular chemistry, controlled architecture has meant something quite different. Because polymerizations are in general statistical processes, conventional polymeric materials are characterized by substantial heterogeneity in chain length, sequence and stereochemistry. Control is exercised in a statistical sense only, and considerable skill is required to control even the average properties of the chain population and the dispersity in those properties.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1557/PROC-218-45DOIArticle
http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8101194&fileId=S1946427400351053PublisherArticle
ORCID:
AuthorORCID
Tirrell, David A.0000-0003-3175-4596
Additional Information: © Materials Research Society 1991.
Series Name:Materials Research Society Symposia Proceedings
Issue or Number:218
Record Number:CaltechAUTHORS:20150326-114459002
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150326-114459002
Official Citation: Maurille J. Fournier, Thomas L. Mason and David A. Tirrell (1990). Comments on the Role of Molecular Genetics in Polymer Materials Science. MRS Proceedings, 218, 45 doi:10.1557/PROC-218-45.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:56136
Collection:CaltechAUTHORS
Deposited By: Anne Hormann
Deposited On:27 Mar 2015 19:47
Last Modified:03 Oct 2019 08:11

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