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Device Modeling of Dye-Sensitized Solar Cells

Bisquert, Juan and Marcus, Rudolph A. (2013) Device Modeling of Dye-Sensitized Solar Cells. In: Multiscale Modelling of Organic and Hybrid Photovoltaics. Topics in Current Chemistry . No.352. Springer , Berlin, pp. 325-395. ISBN 978-3-662-43873-2. https://resolver.caltech.edu/CaltechAUTHORS:20150326-142337714

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Abstract

We review the concepts and methods of modeling of the dye-sensitized solar cell, starting from fundamental electron transfer theory, and using phenomenological transport-conservation equations. The models revised here are aimed at describing the components of the current–voltage curve of the solar cell, based on small perturbation experimental methods, and to such an end, a range of phenomena occurring in the nanoparticulate electron transport materials, and at interfaces, are covered. Disorder plays a major role in the definition of kinetic parameters, and we introduce single particle as well as collective function definitions of diffusion coefficient and electron lifetime. Based on these fundamental considerations, applied tools of analysis of impedance spectroscopy are described, and we outline in detail the theory of recombination via surface states that is successful to describe the measured recombination resistance and lifetime.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1007/128_2013_471DOIArticle
http://link.springer.com/chapter/10.1007%2F128_2013_471PublisherArticle
ORCID:
AuthorORCID
Marcus, Rudolph A.0000-0001-6547-1469
Additional Information:© 2013 Springer-Verlag Berlin Heidelberg. Published online: 28 September 2013. We thank the following agencies for support of this research. Juan Bisquert's research is supported by Ministerio de Educacion y Ciencia under project HOPE CSD2007-00007, Generalitat Valenciana (ISIC/2012/008). Rudolph A. Marcus's research is supported by ARO, ONR and NSF agencies. Rudolph A. Marcus contributed in Sects. 14 and 15 of this chapter.
Funders:
Funding AgencyGrant Number
Ministerio de Educacion y CienciaHOPE CSD2007-00007
Generalitat ValencianaISIC/2012/008
Army Research Office (ARO)UNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
NSFUNSPECIFIED
Series Name:Topics in Current Chemistry
Issue or Number:352
Record Number:CaltechAUTHORS:20150326-142337714
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20150326-142337714
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:56147
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:27 Mar 2015 01:05
Last Modified:22 Nov 2019 09:58

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