Anderson, Donde R. and O'Leary, Daniel J. and Hickstein, Daniel D. and Grubbs, Robert H. (2006) Model compounds of ruthenium-alkene intermediates in olefin metathesis reactions. Abstracts of Papers of the American Chemical Society, 232 . 323-INOR. ISSN 0065-7727. https://resolver.caltech.edu/CaltechAUTHORS:20150407-105805756
Full text is not posted in this repository.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20150407-105805756
Abstract
The development of a model system to study ruthenium-olefin complexes relevant to the mechanism of olefin metathesis is reported. Upon addn. of 1,2-divinylbenzene to (H2IMes)(py2)(Cl)2Ru=CHPh (H2IMes = 1,3-dimesityl-4,5-dihydroimidazol-2- ylidene), two ruthenium-olefin adducts are formed. Based on 1H NMR spectroscopy expts. and X-ray crystallog. anal., these complexes are assigned as side-bound isomers in which the olefin and H2IMes ligands are coordinated cis to each another. Characterization of these complexes as well as other Ru-alkene adducts bearing NHCs will be presented.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| ORCID: |
| ||||
| Additional Information: | © 2006 American Chemical Society. | ||||
| Record Number: | CaltechAUTHORS:20150407-105805756 | ||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150407-105805756 | ||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||
| ID Code: | 56424 | ||||
| Collection: | CaltechAUTHORS | ||||
| Deposited By: | Tony Diaz | ||||
| Deposited On: | 07 Apr 2015 19:25 | ||||
| Last Modified: | 03 Oct 2019 08:13 |
Repository Staff Only: item control page
