Marcus, R. A. (1997) Solvent Dynamics and RRKM Theory of Clusters. In: Chemical reactions and their control on the femtosecond time scale. Advances in chemical physics. No.101. Wiley , New York, NY, pp. 391-408. ISBN 9780471180487. https://resolver.caltech.edu/CaltechAUTHORS:20150421-093424183
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Abstract
In this chapter we consider the problem of reaction rates in clusters (microcanonical) modified by solvent dynamics. The field is a relatively new one, both experimentally and theoretically, and stems from recent work on well-defined clusters. We first review some theories and results for the solvent dynamics of reactions in constant-temperature condensed-phase systems and then describe two papers from our recent work on the adaptation to microcanonical systems. In the process we comment on a number of questions in the constant-temperature studies and consider the relation of those studies to corresponding future studies of clusters.
| Item Type: | Book Section | ||||||
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| Additional Information: | © 1997 John Wiley & Sons, Inc. It is a pleasure to acknowledge the support of this research by the National Science Foundation and the Office of Naval Research. | ||||||
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| Series Name: | Advances in chemical physics | ||||||
| Issue or Number: | 101 | ||||||
| Record Number: | CaltechAUTHORS:20150421-093424183 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20150421-093424183 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 56804 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 21 Apr 2015 16:43 | ||||||
| Last Modified: | 22 Nov 2019 09:58 |
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